Abstract
Single-crystal X-ray diffraction is used to determine the structure of a new compound based on an octahedral cyanide anionic cluster complex of rhenium and a trimethyltin(IV) cation: {(SnMe3)3[Re6Se8(CN)6]} (1). The crystallographic characteristics: space group C2/c, a = 13.9898(14) Å, b =15.334(2) Å, c = 20.761(2) Å, β = 97.75(0)°, V = 4412.91(90) Å3, Z = 4, d x = 3.607 g/cm3, and R = 0.0526. The compound has a framework structure; two porous frameworks with pcu topology interpenetrate each other.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
B. Moulton and M. J. Zaworotko, Chem. Rev., 101, No. 6, 1629–1658 (2001).
J. J. Perry, J. A. Perman, and M. J. Zaworotko, Chem. Soc. Rev., 38, No. 5, 1400–1417 (2009).
N. Stock and S. Biswas, Chem. Rev., 112, No. 2, 933–969 (2012).
P. Schwarz, E. Siebel, R. D. Fischer, et al., Ang. Chem. Int. Ed., 34, No. 11, 1197–1199 (1995).
E. M. Poll, S. Samba, R. D. Fischer, et al., J. Solid St. Chem., 152, No. 1, 286–301 (2000).
K. Yunlu, N. Hock, and R. D. Fischer, Ang. Chem. Int. Ed., 24, No. 10, 879–881 (1985).
P. Schwarz, S. Eller, E. Siebel, et al., Ang. Chem. Int. Ed., 35, Nos. 13/14, 1525–1527 (1996).
L. G. Beauvais, M. P. Shores, and J. R. Long, Chem. Mat., 10, No. 12, 3783 (1998).
M. V. Bennett, M. P. Shores, L. G. Beauvais, and J. R. Long, J. Am. Chem. Soc., 122, No. 28, 6664–6668 (2000).
V. E. Fedorov, N.G. Naumov, Yu.V. Mironov, et al., J. Struct. Chem., 43, No. 4, P. 669–684 (2002).
Y. Kim, S. M. Park, and S. J. Kim, Inorg. Chem. Com., 5, No. 8, 592–595 (2002).
K. A. Brylev, Y. V. Mironov, N. G. Naumov, et al., Inorg. Chem., 43, No. 16, 4833–4838 (2004).
Y. V. Mironov, N. G. Naumov, K. A. Brylev, et al., Ang. Chem. Int. Ed., 43, No. 10, 1297–1300 (2004).
M. S. Tarasenko, N. G. Naumov, A. V. Virovets, et al., J. Struct. Chem., 46,Suppl., S137–S144 (2005).
M. S. Tarasenko, A. Y. Ledneva, N. G. Naumov, et al., J. Cluster Sci., 16, No. 3, 353–365 (2005).
M. S. Tarasenko, A. Yu. Ledneva, N. V. Kurat’eva, et al., Koordinats. Khim., 33, No. 12, P. 876–885 (2007).
N. G. Naumov, A. V. Virovets, N. V. Podberezskaya, and V. E. Fedorov, J. Struct. Chem., 38, No. 6, 857–863 (1997).
G. M. Sheldrick, Bruker-Nonius SADABS, Program for Empirical X-ray Absorption Correction (1990–2004).
Bruker Version 6.22, Bruker AXS Inc. Madison, WI, USA (2003).
F. H. Allen, Acta Crystallogr. B-Struct. Sci., 58, 380–388 (2002).
V. A. Blatov, Newsletter IUCr CompComm., 7, No. 4 (2006).
N. G. Naumov, A. V. Virovets, and V. E. Fedorov, J. Struct. Chem., 41, No. 3, 499 (2000).
N. G. Naumov, E. V. Ostanina, A. V. Virovets, et al., Izv. Akad. Nauk, Ser. Khim., No. 5, 799–803 (2002).
M. O’Keeffe, M. A. Peskov, S. J. Ramsden, and O. M. Yaghi, Acc. Chem. Res., 41, No. 12, 1782–1789 (2008).
V. A. Blatov, L. Carlucci, G. Ciani, and D. M. Proserpio, Crystengcomm., 6, 377–395 (2004).
È. G. Perevalova, M. D. Reshetova, and P. N. Ostapchuk, Metallorgan. Khim., 3, 105 (1990).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text Copyright © 2013 by A. Yu. Ledneva, A. V. Virovets, N. G. Naumov
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 54, No. 4, pp. 768–772, July–August, 2013.
Rights and permissions
About this article
Cite this article
Ledneva, A.Y., Virovets, A.V. & Naumov, N.G. Interpenetrating frameworks in the structure of the [(SnMe3)3Re6Se8(CN)6] cluster complex. J Struct Chem 54, 815–819 (2013). https://doi.org/10.1134/S0022476613040252
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476613040252