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A zwitterionic monoalkylated derivative of [Pt2(μ-S)2(PPh3)4] from 1,3-propanesultone

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Abstract

Reaction of dinuclear platinum(II) sulfido complex [Pt2(μ-S)2(PPh3)4] with 1,3-propanesultone gives the novel zwitterionic monoalkylated thiolate complex [Pt2(μ-S){μ-S(CH2)3SO3}·(PPh3)4], which was characterized by NMR spectroscopy, electrospray ionisation mass spectrometry, and a single crystal X-ray structure determination. Crystals are monoclinic, space group P2(1)/c with unit cell dimensions a = 16.8957(3) Å, b = 15.5031(3) Å, c = 28.0121(5) Å, β = 99.780(1)°, for Z = 4.

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Authors and Affiliations

  1. Department of Chemistry, University of Waikato, Hamilton, New Zealand

    O. T. Ujam, W. Henderson & B. K. Nicholson

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  1. O. T. Ujam
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  2. W. Henderson
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  3. B. K. Nicholson
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Correspondence to W. Henderson.

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Original Russian Text Copyright © 2013 by O. T. Ujam, W. Henderson, B. K. Nicholson

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 54, No. 3, pp. 470–474, May–June, 2013

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Ujam, O.T., Henderson, W. & Nicholson, B.K. A zwitterionic monoalkylated derivative of [Pt2(μ-S)2(PPh3)4] from 1,3-propanesultone. J Struct Chem 54, 523–527 (2013). https://doi.org/10.1134/S0022476613030074

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  • DOI: https://doi.org/10.1134/S0022476613030074

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