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Theoretical investigation of ozone hydrate formation conditions

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Abstract

Structural, dynamic, and thermodynamic properties of ozone, oxygen, and mixed ozone-oxygen hydrates are investigated. The thermodynamic stability regions of these hydrates are found. Ozone can form hydrates at ambient pressure and temperatures below 230 K. Strong dependence of the binary hydrate formation pressure on the ozone concentration in the gas phase is shown. In the formation of the hydrate, ozone concentrates in the hydrate phase. At an ozone concentration of 5 mol.% in the gas phase, the ozone content in the hydrate reaches 40%.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    O. S. Subbotin, T. P. Adamova & V. R. Belosludov

  2. Institute for Materials Research, Sendai, Japan

    R. V. Belosludov, H. Mizuseki & Y. Kawazoe

Authors
  1. O. S. Subbotin
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  2. T. P. Adamova
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  3. R. V. Belosludov
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  4. H. Mizuseki
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  5. Y. Kawazoe
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  6. V. R. Belosludov
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Corresponding author

Correspondence to O. S. Subbotin.

Additional information

Original Russian Text Copyright © 2012 by O. S. Subbotin, T. P. Adamova, R. V. Belosludov, H. Mizuseki, Y. Kawazoe, V. R. Belosludov

Devoted to the Jubilee of Academician F. A. Kuznetsov

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 4, pp. 640–646, July–August, 2012.

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Subbotin, O.S., Adamova, T.P., Belosludov, R.V. et al. Theoretical investigation of ozone hydrate formation conditions. J Struct Chem 53, 627–633 (2012). https://doi.org/10.1134/S0022476612040026

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  • DOI: https://doi.org/10.1134/S0022476612040026

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