Abstract
X-ray diffraction is used to determine the crystal and molecular structure of the complex of N-(1-silatranylmethyl)-3,5-dimethylpyrazole with cobalt dichloride (I). This is yet another example of the participation of the endocyclic oxygen atom of the silatrane fragment in complexation with a metal atom. Metal dichloride interconnects two heterocyclic systems of dimethylpyrazole (DMP) and silatrane (Sa). The coordination polyhedron of the cobalt atom is a tetrahedron.
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Original Russian Text Copyright © 2012 by M. G. Voronkov, É. A. Zel’bst, A. D. Vasiliev, A. S. Soldatenko, Yu. I. Bolgova, O. M. Trofimova
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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 3, pp. 619–622, May–June, 2012.
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Voronkov, M.G., Zel’bst, É.A., Vasiliev, A.D. et al. Crystal and molecular structure of the complex of N-(1-silatranylmethyl)-3,5-dimethylpyrazole with cobalt dichloride. J Struct Chem 53, 614–617 (2012). https://doi.org/10.1134/S0022476612030316
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DOI: https://doi.org/10.1134/S0022476612030316