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Crystal structure of nickel(II) bis-(1,1,1,-trifluoro-5,5-dimethyl-2,4-hexanedionate)-1,3-diaminopropane

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Abstract

The structure of the complex of nickel(II) bis-(1,1,1-trifluoro-5,5-dimethyl-2,4-hexanedionate) with 1,3-diaminopropane is determined by single crystal X-ray diffraction at a temperature of 150 K. Crystallographic data for C20H34F6N2NiO5: a = 17.5446(8) Å, b = 18.1171(10) Å, c = 18.6654(7) Å, β = 115.4150(10)°, space group C2/c, V = 5358.8(4) Å3, Z = 8, d calc = 1.376 g/cm3, R = 0.0435. The structure is molecular; the metal atom coordinates four oxygen atoms of two β-diketonate ligands and two nitrogen atoms of propylenediamine. In the crystal, the molecules are bonded only by van der Vaals interactions.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    S. I. Dorovskikh, D. A. Piryzev, A. I. Smolentsev & N. B. Morozova

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  1. S. I. Dorovskikh
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  2. D. A. Piryzev
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  3. A. I. Smolentsev
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  4. N. B. Morozova
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Correspondence to S. I. Dorovskikh.

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Original Russian Text Copyright © 2012 by S. I. Dorovskikh, D. A. Piryzev, A. I. Smolentsev, N. B. Morozova

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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 3, pp. 615–618, May–June, 2012.

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Dorovskikh, S.I., Piryzev, D.A., Smolentsev, A.I. et al. Crystal structure of nickel(II) bis-(1,1,1,-trifluoro-5,5-dimethyl-2,4-hexanedionate)-1,3-diaminopropane. J Struct Chem 53, 610–613 (2012). https://doi.org/10.1134/S0022476612030304

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  • DOI: https://doi.org/10.1134/S0022476612030304

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