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Crystal structure of bis[2-((E)-(p-tolylimino) methyl)-6-bromo-4-chlorophenol]copper(II)

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Abstract

A new complex CuL2 1 [HL = 2-((E)-(p-tolylimino) methyl)-6-bromo-4-chlorophenol] is obtained and characterized using the single crystal X-ray diffraction analysis. The crystal belongs to the monoclinic system, P21/c space group, with a = 13.3203(13) Å, b = 12.3052(11) Å, c = 17.8664(17) Å, β = 105.3420(10)°, V = 2824.1(5) Å3, Z = 4, D c = 1.672 g/cm3, R 1 = 0.0686. The geometry around copper(II) is intermediate between square planar and tetrahedral. The units of the complex are linked via weak intermolecular Br…Br contracts, leading to the formation of one-dimension (1D) chains along the b axis; the multipoint Cu…Cl intermolecular interactions extend the 1D chain into a 2D layer.

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  1. Department of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Shaanxi, China

    X. H. Pu

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  1. X. H. Pu
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Correspondence to X. H. Pu.

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Original Russian Text Copyright © 2012 by X. H. Pu

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 53, No. 3, pp. 608–610, May–June, 2012.

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Pu, X.H. Crystal structure of bis[2-((E)-(p-tolylimino) methyl)-6-bromo-4-chlorophenol]copper(II). J Struct Chem 53, 603–605 (2012). https://doi.org/10.1134/S0022476612030286

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  • DOI: https://doi.org/10.1134/S0022476612030286

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