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Crystal structure of a new mononuclear complex of Mn(II) with a bbbi ligand (bbbi = 1,4-bis(benzimidazol-1-yl)-2-butene)

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Abstract

A new mononuclear complex Mn(bbbi)2(H2O)4(ClO4)2·(bbbi)2·(H2O)2 1 (bbbi = 1,4-bis(benzimidazol-1-yl)-2-butene) is synthesized under hydrothermal conditions and characterized by IR spectroscopy, elemental analysis, and single crystal X-ray structural analysis. Crystal data for 1: triclinic, \(P\bar 1\), a = 8.8478(7) Å, b = 15.0550(11) Å, c = 16.4310(12) Å, α = 108.657(7)°, β = 104.044(7)°, Γ = 99.317(7)°, V = 1942.2(3) Å3, Z = 1, final R = 0.0621. Each manganese atom is octahedrally coordinated by four aqua ligands and two nitrogen atoms of two distinct bbbi ligands. The molecule is stabilized by hydrogen bonding and π…π interactions.

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References

  1. R. J. Kuppler, D. J. Timmons, Q. R. Fang, J. R. Li, T. A. Makal, M. D. Young, D. Q. Yuan, D. Zhao, W. J. Zhuang, and H. C. Zhou, Coord. Chem. Rev., 253, 3042 (2009)

    Article  CAS  Google Scholar 

  2. O. M. Yaghi, H. Li, C. Davis, D. Richardson, and T. L. Groy, Acc. Chem. Res., 31, 474 (1998)

    Article  CAS  Google Scholar 

  3. S. S. Y. Chui, S. M. F. Lo, J. P. H. Charmant, A. G. Orpen, and I. D. Williams, Science, 283, 1148 (1999)

    Article  CAS  Google Scholar 

  4. M. J. Zaworotko, Nature Chemistry, 1, 267 (2009)

    Article  CAS  Google Scholar 

  5. R. Banerjee, A. Phan, B. Wang, C. Knobler, H. Furukawa, M. O’Keeffe, and O. M. Yaghi, Science, 319, 939 (2008).

    Article  CAS  Google Scholar 

  6. O. K. Farha and J. T. Hupp, Acc. Chem. Res., 43, 1166 (2010)

    Article  CAS  Google Scholar 

  7. J. R. Li, R. J. Kuppler, and H. C. Zhou, Chem. Soc. Rev., 38, 1477 (2009)

    Article  CAS  Google Scholar 

  8. H. Masui, Coord. Chem. Rev., 219, 957 (2001)

    Article  Google Scholar 

  9. J.-R. Li, A. A. Yakovenko, W. Lu, D. J. Timmons, W. Zhuang, D. Yuan, and H. C. Zhou, J. Am. Chem. Soc., 132, 17599 (2010)

    Article  CAS  Google Scholar 

  10. A. V. Virovets, D. A. Piryazev, E. V. Lider, A. I. Smolentsev, S. F. Vasilevskii, and L. G. Lavrenova, J. Struct. Chem., 51, 92 (2010).

    Article  CAS  Google Scholar 

  11. J. Fan and B. E. Hanson, Inorg. Chem., 44, 6988 (2005)

    Google Scholar 

  12. F. M. Nie, J. Chen, Z. Li, and F. Lu, J. Coord. Chem., 63, 1711 (2010)

    Article  CAS  Google Scholar 

  13. X. L. Wang, C. Qin, E. B. Wang, Z. M. Su, L. Xu, and S. R. Battern, Chem. Commun., 38, 4789 (2005)

    Article  Google Scholar 

  14. X. L. Wang, C. Qin, E. B. Wang, et al., Angew. Chem. Int. Ed., 44, 5824 (2005)

    Article  CAS  Google Scholar 

  15. Y. F. Qi, Y. G. Li, C. Qin, E. B. Wang, H. Jin, D. R. Xiao, X. L. Wang, and S. Chang, Inorg. Chem., 46, 3217 (2007)

    Article  CAS  Google Scholar 

  16. Y. G. Wei, B. B. Xu, C. L. Barnes, and Z. H. Peng, J. Am. Chem. Soc., 123, 4083 (2001)

    Article  CAS  Google Scholar 

  17. T. Akutagawa, D. Imai, S. I. Noro, L. Cronin, and T. Nakamura, Inorg. Chem., 45, 8628 (2006)

    Article  CAS  Google Scholar 

  18. J. Q. Chen, Y. P. Cai, H. C. Fang, Z. Y. Zhou, X. L. Zhan, G. Zhao, and Z. Zhang, Cryst. Growth Des., 9, 1605 (2009).

    Article  CAS  Google Scholar 

  19. M. E. Kelly, A. Dietruch, S. G. Ruiz, B. Kalinowski, G. N. Kaluderovic, T. Müller, H. Schmidt, et al., Organometallics, 27, 4917 (2008).

    Article  CAS  Google Scholar 

  20. L. L. Li, R. X. Yuan, L. L. Liu, Z. G. Ren, A. X. Zheng, H. J. Cheng, H. X. Li, and J. P. Lang, Cryst. Growth Des., 10, 1929 (2010).

    Article  CAS  Google Scholar 

  21. Q. Chang, X. R. Meng, Y. L. Song, and H. W. Hou, Chinese J. Chem., 23, 725 (2005).

    Article  CAS  Google Scholar 

  22. G. M. Sheldrick, SADABS, Program for Empirical Absorption Correction of Area Detector Data, Univ. Göttingen, Germany (1996).

    Google Scholar 

  23. G. M. Sheldrick, SHELXLS-97, Program for X-ray Crystal Structure Solution, Univ. Göttingen, Germany (1997).

    Google Scholar 

  24. G. M. Sheldrick, SHELXL-97, Program for X-ray Crystal Structure Refinement, Univ. Göttingen, Germany (1997).

    Google Scholar 

  25. H. X. Yang, X. R. Meng, Y. Liu, H. W. Hou, Y. T. Fan, and X. Q. Shen, J. Solid State Chem., 181, 2178 (2008)

    Article  CAS  Google Scholar 

  26. P. F. Rodesiler and E. L. Amma, Inorg. Chem., 11, 388 (1972).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, Tangshan, Hebei Province, P. R. China, 063009

    G. -H. Cui, T. -F. Liu, C. -H. He & C. -H. Jiao

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  1. G. -H. Cui
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  2. T. -F. Liu
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  3. C. -H. He
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  4. C. -H. Jiao
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Correspondence to G. -H. Cui.

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Original Russian Text Copyright © 2012 by G.-H. Cui, T.-F. Liu, C.-H. He, C.-H. Jiao

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 53, No. 3, pp. 603–607, May–June, 2012.

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Cui, G.H., Liu, T.F., He, C.H. et al. Crystal structure of a new mononuclear complex of Mn(II) with a bbbi ligand (bbbi = 1,4-bis(benzimidazol-1-yl)-2-butene). J Struct Chem 53, 598–602 (2012). https://doi.org/10.1134/S0022476612030274

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  • DOI: https://doi.org/10.1134/S0022476612030274

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