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Re-determination of the crystal structure of heyrovskyite mineral Pb6Bi2S9 (Kudryavyi Volcano, Iturup Island, Kurils, Russia)

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Abstract

Heyrovskyite mineral Pb6Bi2S9 from fumarole exhalations of the Kudryavyi volcano (Iturup island, Kurils, Russia) is studied by X-ray crystallography (Bruker Nonius X8 Apex with a 4K CCD detector, R = 0.0405). Unit cell parameters are: a = 4.1457(1) Å, b = 13.7421(5) Å, c = 31.5005(12) Å, V = 1794.6(1) Å3, Z = 4, d x = 7.216 g/cm3, Cmcm space group, R=0.0405. The resulted structure is similar to the known structures of heyrovskyites from other deposits with some variation in the cation composition.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    N. V. Pervukhina, S. V. Borisov, S. A. Magarill & N. V. Kuratieva

  2. Institute of Geology of Ore Deposits, Petrography, Mineralogy, and Geochemistry, Russian Academy of Sciences, Moscow, Russia

    N. N. Mozgova & I. V. Chaplygin

Authors
  1. N. V. Pervukhina
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  2. S. V. Borisov
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  3. S. A. Magarill
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  4. N. V. Kuratieva
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  5. N. N. Mozgova
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  6. I. V. Chaplygin
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Corresponding author

Correspondence to N. N. Mozgova.

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Original Russian Text Copyright © 2012 by N. V. Pervukhina, S. V. Borisov, S. A. Magarill, N. V. Kuratieva, N. N. Mozgova, I. V. Chaplygin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 3, pp. 593–597, May–June, 2012.

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Pervukhina, N.V., Borisov, S.V., Magarill, S.A. et al. Re-determination of the crystal structure of heyrovskyite mineral Pb6Bi2S9 (Kudryavyi Volcano, Iturup Island, Kurils, Russia). J Struct Chem 53, 588–592 (2012). https://doi.org/10.1134/S0022476612030250

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  • DOI: https://doi.org/10.1134/S0022476612030250

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