Skip to main content
SpringerLink
Log in

Complex salts with participation of [Rh(NH3)6]3+ cations

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Four complex salts with the polyatomic [Rh(NH3)6]3+ cation are synthesized and studied by X-ray diffraction. The crystallographic characteristics of [Rh(NH3)6](WO4)Cl are determined and the structures of [Rh(NH3)6]Cl3, [Rh(NH3)6](ReO4)3·2H2O, and [Rh(NH3)6](MoO4)Cl·3H2O are solved. The features of mutual packing of the fragments are studied.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. H. Allen, Acta Crystallogr., B58, 380–388 (2002).

    CAS  Google Scholar 

  2. Inorganic Crystal Structure Database, ICSD, Release 2010, Fashinformationszentrum Karlsruhe, D-1754 Eggenstein-Leopoldshafen, Germany (2010).

  3. Powder Diffraction File, PDF-2/Release 2009, International Centre for Diffraction Data, USA (2009).

  4. M. Gorol, N. C. Mosch-Zenetti, M. Noltemeyer, et al., Z. Anorg. Allg. Chem., 626, 2318 (2000).

    Article  CAS  Google Scholar 

  5. S. M. Jörgensen, J. Prakt. Chem., 44, 48 (1891).

    Article  Google Scholar 

  6. S. M. Jörgensen, J. Prakt. Chem., 44, 63 (1891).

    Article  Google Scholar 

  7. I. A. Baidina, E. Yu. Filatov, E. V. Makotchenko, and A. I. Smolentzev, J. Struct. Chem., 53, No. 1, 112–118 (2012).

    Article  CAS  Google Scholar 

  8. G. M. Sheldrick, Acta Crystallogr., A64, No. 1, 112–122 (2008).

    CAS  Google Scholar 

  9. A. C. Larson and R. B. Von Dreele, “GSAS” LANSCE, MS-H805, Los Alamos Natl. Lab. Los Alamos, NM 87545.

  10. S. V. Borisov, J. Struct. Chem., 27, No. 3, 486–488 (1986).

    Article  Google Scholar 

  11. S. A. Gromilov, Determination of Structural Motifs of Coordination Compounds from Accurate X-Ray Diffraction Data of Polycrystals, Diss. … Doc. of Chem. Sc., Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk (2005).

  12. S. A. Gromilov, I. A. Baidina, V. I. Alexeyev, et al., Zh. Neorg. Khim., 35, No. 3, 682–684 (1990).

    CAS  Google Scholar 

  13. S. A. Gromilov, S. P. Khranenko, I. A. Baidina, et al., J. Struct. Chem., 43, No. 1, 142–146 (2002).

    Article  Google Scholar 

  14. S. A. Gromilov and S. V. Borisov, J. Struct. Chem., 44, No. 4, 664–680 (2003).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    S. P. Khranenko, E. A. Bykova, A. V. Alexeyev & S. A. Gromilov

  2. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg, Russia

    A. P. Tyutyunnik

  3. Scientific and Educational Complex “Nanosystems and Advanced Materials.”, Novosibirsk State University, Novosibirsk, Russia

    A. V. Alexeyev & S. A. Gromilov

Authors
  1. S. P. Khranenko
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E. A. Bykova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. V. Alexeyev
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. P. Tyutyunnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. S. A. Gromilov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. A. Gromilov.

Additional information

Original Russian Text Copyright © 2012 by S. P. Khranenko, E. A. Bykova, A. V. Alexeyev, A. P. Tyutyunnik, S. A. Gromilov

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 3, pp. 527–533, May–June, 2012.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Khranenko, S.P., Bykova, E.A., Alexeyev, A.V. et al. Complex salts with participation of [Rh(NH3)6]3+ cations. J Struct Chem 53, 521–526 (2012). https://doi.org/10.1134/S0022476612030158

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476612030158

Keywords

Search

Navigation