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Structure and characterization of a 1d double chain copper(II) complex {[Cu(BIX)2(H2O)2](PhCOO)2} n

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Abstract

A novel copper(II) complex {[Cu(BIX)2(H2O)2](PhCOO)2} n (1) (BIX = 1,4-bis(imidazole-1-methyl))-benzene) is synthesized and characterized by elemental analysis, IR, TG, and single crystal X-ray diffraction. Complex 1 crystallizes in the triclinic crystal system with the P-1 space group, Z = 1, a = 9.465(2) Å, b = 9.703(2) Å, c = 12.060(2) Å, α = 77.26(3)°, β = 70.37(3)°, γ = 67.14(3)°, and V = 956.1(3) Å3. The crystal structural analysis of complex 1 shows that the copper center is six-coordinated in an elongated octahedral geometry by four N atoms from four different BIX and two O atoms from two water molecules; two neighboring Cu(II) cations are bridged by two BIX extending into an infinite 1D double chain structure.

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, Tangshan, Hebei, P. R. China

    G. -H. Cui, J. -C. Geng, T. -F. Liu, X. Peng, C. -H. He & C. -H. Jiao

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  1. G. -H. Cui
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  2. J. -C. Geng
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  3. T. -F. Liu
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  4. X. Peng
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  5. C. -H. He
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  6. C. -H. Jiao
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Correspondence to G. -H. Cui.

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Original Russian Text Copyright © 2012 by G.-H. Cui, J.-C. Geng, T.-F. Liu, X. Peng, C.-H. He, C.-H. Jiao

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 53, No. 3, pp. 515–519, May–June, 2012.

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Cui, G.H., Geng, J.C., Liu, T.F. et al. Structure and characterization of a 1d double chain copper(II) complex {[Cu(BIX)2(H2O)2](PhCOO)2} n . J Struct Chem 53, 509–513 (2012). https://doi.org/10.1134/S0022476612030134

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  • DOI: https://doi.org/10.1134/S0022476612030134

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