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Structure of complex salts [Co(NH3)6][Rh(NO2)6] and [Co(NH3)6][(NO2)3Rh(μ-NO2)1+x (μ-OH)2−x Rh(NO2)3]·(2-x)(H2O), x = 0.17

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Abstract

The structures of two salts [Co(NH3)6][Rh(NO2)6] (I) and [Co(NH3)6][(NO2)3Rh(μ-NO2)1+x (μ-OH)2−x Rh(NO2)3]·(2−x)(H2O), x = 0.17 (II) are solved. Single crystals of the salts are obtained by the counter diffusion method through the gel of aqueous solutions of [Co(NH3)6]Cl3 and Na3[Rh(NO2)6]. The structure of [Co(NH3)6][Rh(NO2)6] is consistent with the diffraction data for a polycrystalline sample of poorly soluble fine salt formed in the exchange reaction between aqueous solutions of [Co(NH3)6]Cl3 and Na3[Rh(NO2)6]. The structure of [Co(NH3)6][(NO2)3Rh(μ-NO2)1+x (μ-OH)2−x Rh(NO2)3]·(2−x)(H2O), x = 0.17 exhibits the stabilizing effect of a large cation in the formation of novel, unknown previously coordination ions: [(NO2)3Rh(μ-NO2)(μ-OH)2Rh(NO2)3]3− and [(NO2)3Rh(μ-NO2)2(μ-OH)Rh(NO2)3]3−.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    A. I. Gubanov, N. V. Kuratieva, E. Yu. Filatov & S. V. Korenev

  2. Novosibirsk State University, Novosibirsk, Russia

    A. I. Gubanov, N. V. Kuratieva, E. Yu. Filatov & S. V. Korenev

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  1. A. I. Gubanov
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  2. N. V. Kuratieva
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  3. E. Yu. Filatov
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  4. S. V. Korenev
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Correspondence to A. I. Gubanov.

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Original Russian Text Copyright © 2012 by A. I. Gubanov, N. V. Kuratieva, E. Yu. Filatov, S. V. Korenev

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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 3, pp. 508–514, May–June, 2012.

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Gubanov, A.I., Kuratieva, N.V., Filatov, E.Y. et al. Structure of complex salts [Co(NH3)6][Rh(NO2)6] and [Co(NH3)6][(NO2)3Rh(μ-NO2)1+x (μ-OH)2−x Rh(NO2)3]·(2-x)(H2O), x = 0.17. J Struct Chem 53, 503–508 (2012). https://doi.org/10.1134/S0022476612030122

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  • DOI: https://doi.org/10.1134/S0022476612030122

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