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The double salt tris(diisopropylammonium) tetrachloridoferrate(III) dichloride: Synthesis, crystal structure, and vibrational spectra

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Abstract

Tris(diisopropylammonium)tetrachloridoferrate(III) dichloride crystallizes in the monoclinic space group P21/c (a = 7.6685(2) Å, b = 17.6079(3) Å, c = 23.3217(4) Å, β = 91.396(2)°, V = 3148.1(1) Å3, Z = 4, T = 113 K) with three diisopropylammonium cations (dip), one tetrachloridoferrate(III) anion, and two chloride anions in the asymmetric unit. The dip cations and the chloride anions form hydrogen bonded one-dimensional polymers along [010]. The tetrachloridoferrate(III) anion, habituated in between these chains, is not involved in any hydrogen bonding. The structural characterization is supported by infrared and Raman spectroscopic data.

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  1. Institut f. Anorganische Chemie und Strukturchemie, Lehrstuhl II: Material- und Strukturforschung, Heinrich-Heine-Universität Düsseldorf, Düsseldorf, Germany

    G. L. Reiss

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  1. G. L. Reiss
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Original Russian Text Copyright © 2012 by G. L. Reiss

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 53, No. 2, pp. 400–403, March–April, 2012.

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Reiss, G.L. The double salt tris(diisopropylammonium) tetrachloridoferrate(III) dichloride: Synthesis, crystal structure, and vibrational spectra. J Struct Chem 53, 403–407 (2012). https://doi.org/10.1134/S0022476612020308

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