Abstract
By single crystal X-ray analysis, the atomic structure of the crystals of bis-phenanthrolinium hexachlorotellurate(IV) dihydrate (C12H9N2)2 TeBr6·2H2O (a = 7.4846(5) Å, b = 13.792(1) Å, c = 14.532(1) Å, β = 99.857(2)°, space group P21/c, Z = 2, d x = 2.259 g/cm3) is determined. The crystal structure is formed from separate anions [TeBr6]2−, cations of phenanthrolinium (C12H9N2)+, and water molecules. The electronic and geometrical aspects determining the spectral-luminescent and thermochromic properties of the complex are discussed.
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J. S. Nagpal, S. V. Godbole, G. Varadharajan, and A. G. Page, Radiat. Protect. Dosimetry, 80, No. 4, 417 (1998).
G. Blasse, Chem. Phys. Lett., 104, Nos. 2/3, 160 (1984).
G. Blasse, Rev. Inorg. Chem., 5, No. 4, 319 (1983).
A. Vogler, A. Paukner, and H. Kunkely, Coord. Chem. Rev., 97, 285 (1990).
A. Vogler and H. Nikol, Pure Appl. Chem., 64, No. 9, 1311 (1992).
E. W. J. L. Oomen, W. M. A. Smit, and G. Blasse, J. Phys. C. Solid State Phys., 19, 3263 (1986).
A. G. Mirochnik, B. V. Bukvetskii, T. V. Storozhuk, and V. E. Karasev, Zh. Neorg. Khim., 48, No. 4, 582 (2003).
T. V. Storozhuk, B. V. Bukvetskii, A. G. Mirochnik, and V. E. Karasev, J. Struct. Chem., 44, No. 5, 880–884 (2003).
A. K. Babko and I. V. Pyatnitskii, Quantitative Analysis [in Russian], Goskhimizdat, Moscow (1956).
Bruker (1998), SMART and SAINT-Plus, Versions 5.0, Data Collektion and Processing Software for the SMART Sistem, Bruker AXS Inc.-Madison, Wisconsin, USA.
G. M. Sheldrick, SHELXTL/PC, Versions 5.10, An Integrated System for Soling, Refining and Displaying Crystal Structures From Diffraction Data, Bruker AXS Inc.-Madison, Wisconsin, USA (1998).
B. V. Bukvetskii and A. G. Mirochnik, J. Struct. Chem., 46, No. 4, 672–682 (2005).
I. B. Bersuker, The Jahn-Teller Effect and Vibronic Interactions in Modern Chemistry [in Russian], Nauka, Moscow (1987).
A. G. Mirochnik, B. V. Bukvetskii, E. V. Gukhman, and V. E. Karasev, J. Fluoresc., 13, No. 2, 157–162 (2003).
B. V. Bukvetskii, E. V. Fedorenko, A. G. Mirochnik, and V. E. Karasev, J. Struct. Chem., 48, No. 6, 1148–1151 (2007).
P. Naumov, S. C. Lee, N. Ishizawa, et al., J. Phys. Chem. A, 113, 11354–11366 (2009).
D. J. Stufkens, Rec. Trav. Chim., 89, No. 11, 1185 (1970).
A. Vogler and A. Paukner, J. Photochem. Photobiol., A: Chemistry, 46, 227 (1989).
T. V. Sedakova, A. G. Mirochnik, and V. E. Karasev, Opt. Spektroskop., 105, No. 4, 584 (2008).
G. Blasse, Prog. Solid State Chem., 18, No. 2, 79 (1988).
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Original Russian Text Copyright © 2012 by B. V. Bukvetskii, T. V. Sedakova, A. G. Mirochnik
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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 2, pp. 307–313, March–April, 2012.
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Bukvetskii, B.V., Sedakova, T.V. & Mirochnik, A.G. Crystal structure, luminescent and thermochromic properties of bis-1,10-phenan-throlinium hexachlorotellurate(IV) dihydrate. J Struct Chem 53, 306–312 (2012). https://doi.org/10.1134/S002247661202014X
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DOI: https://doi.org/10.1134/S002247661202014X