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Crystal structures of two solvates of molybdenum octahedral clusters: (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH3CN and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH2Cl2

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Abstract

Crystal structures of two solvates (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH3CN (1) and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH2Cl2 (2) are determined. Both compounds contain cluster [Mo6Cl8(O3SC6H4CH3)6]2− anions. Molybdenum atoms are coordinated with monodentate carboxylate ligands (Mo-O 2.101(3)–2.110(3) Å in 1; 2.088(7)–2.109(2) Å in 2).

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    M. N. Sokolov, M. A. Mikhailov, P. A. Abramov & V. P. Fedin

  2. Novosibirsk State University, Novosibirsk, Russia

    M. N. Sokolov, P. A. Abramov & V. P. Fedin

Authors
  1. M. N. Sokolov
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  2. M. A. Mikhailov
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  3. P. A. Abramov
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  4. V. P. Fedin
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Correspondence to M. N. Sokolov.

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Original Russian Text Copyright © 2012 by M. N. Sokolov, M. A. Mikhailov, P. A. Abramov, and V. P. Fedin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 1, pp. 200–204, January–February, 2012.

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Sokolov, M.N., Mikhailov, M.A., Abramov, P.A. et al. Crystal structures of two solvates of molybdenum octahedral clusters: (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH3CN and (Bu4N)2[Mo6Cl8(O3SC6H4CH3)6]·2CH2Cl2 . J Struct Chem 53, 197–201 (2012). https://doi.org/10.1134/S0022476612010283

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  • DOI: https://doi.org/10.1134/S0022476612010283

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