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Crystal and molecular structure of the complex of 2-(1-silatranylmethylthio)-4,5-benzo-1,3-thiazole with CoCl2 and MeCN

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Abstract

The crystal and molecular structure of the complex of 2-(1-silatranylmethylthio)-4,5-benzo-1,3-thiazole with CoCl2 and MeCN (I) is determined by single crystal X-ray diffraction. The geometry of the silatranylmethyl moiety in complex I is compared to the geometry of 1-(2′-benzthiazolylthiomethyl) silatrane. Molecular packing in the crystal is analyzed.

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Authors and Affiliations

  1. A. E. Favorsky Institute of Chemistry, Siberian Division, Russian Academy of Sciences, Irkutsk, Russia

    M. G. Voronkov, A. S. Soldatenko, Yu. I. Bolgova & O. M. Trofimova

  2. East Siberian Academy of Education, Irkutsk, Russia

    É. A. Zel’bst

  3. L. V. Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Russia

    A. D. Vasiliev

Authors
  1. M. G. Voronkov
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  2. É. A. Zel’bst
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  3. A. D. Vasiliev
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  4. A. S. Soldatenko
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  5. Yu. I. Bolgova
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  6. O. M. Trofimova
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Corresponding author

Correspondence to É. A. Zel’bst.

Additional information

Original Russian Text Copyright © 2012 by M. G. Voronkov, É. A. Zel’bst, A. D. Vasiliev, A. S. Soldatenko, Yu. I. Bolgova, and O. M. Trofimova

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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 1, pp. 196–199, January–February, 2012.

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Voronkov, M.G., Zel’bst, É.A., Vasiliev, A.D. et al. Crystal and molecular structure of the complex of 2-(1-silatranylmethylthio)-4,5-benzo-1,3-thiazole with CoCl2 and MeCN. J Struct Chem 53, 193–196 (2012). https://doi.org/10.1134/S0022476612010271

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  • DOI: https://doi.org/10.1134/S0022476612010271

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