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[Ni(en)3](ReO4)2: Synthesis, crystal structure and thermal properties

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Abstract

The crystal structure of [Ni(en)3](ReO4)2 (en is ethylenediamine) is studied: a = 8.3997(2)Å, b = 15.6167(5)Å, c = 14.2406(4)Å, β = 100.378(1)°, V = 1837.46(9) OA3, P21/c space group, Z = 4, and d x = 2.673 g/cm3. It is shown that packing of the complex cations can be considered as single-layer pseudohexagonal. Thermal decomposition of the salt in a hydrogen atmosphere at 550°C is used to obtain a mixture of nickel with a nanocrystalline Re0.87Ni0.13 solid solution (a = 2.733(2)Å, c = 4.400(3)Å, P63/mmc space group; CSR size is ∼14 nm).

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Authors and Affiliations

  1. A.V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    E. A. Bykova, S. P. Khranenko & S. A. Gromilov

  2. Research and Education Complex “Nanosystems and Modern Materials,”, Novosibirsk State University, Novosibirsk, Russia

    S. A. Gromilov

Authors
  1. E. A. Bykova
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  2. S. P. Khranenko
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  3. S. A. Gromilov
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Correspondence to E. A. Bykova.

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Original Russian Text Copyright © 2012 by E. A. Bykova, S. P. Khranenko, and S. A. Gromilov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 1, pp. 186–190, January–February, 2012.

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Bykova, E.A., Khranenko, S.P. & Gromilov, S.A. [Ni(en)3](ReO4)2: Synthesis, crystal structure and thermal properties. J Struct Chem 53, 184–188 (2012). https://doi.org/10.1134/S0022476612010258

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  • DOI: https://doi.org/10.1134/S0022476612010258

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