Abstract
The crystal structures of [CuL](NO3)(ReO4) and [CuL](ReO4)2 (L is 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-en) are studied. The square coordination of the copper atom in [CuL](NO3)(ReO4) is completed to a distorted octahedron by two oxygen atoms: Cu…O (ReO −4 ) 2.393 Å and Cu…O (NO −3 ) 2.685 Å, and that in [CuL](ReO4)2, by Cu…O(ReO −4 ) 2.468 Å and 2.697 Å. The products of thermolysis of the salts in a hydrogen atmosphere at 800°C are mixtures of nanocrystalline metal powders with coherent scattering regions of ∼45 nm.
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Original Russian Text Copyright © 2012 by E. A. Bykova, S. P. Khranenko, E. Yu. Semitut, and S. A. Gromilov
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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 1, pp. 142–148, January–February, 2012.
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Bykova, E.A., Khranenko, S.P., Semitut, E.Y. et al. Crystal structure of [CuL](NO3)(ReO4) and [CuL](ReO4)2 (L = 4,6,6-trimethyl-1,9-diamino-3,7-diazanon-3-en). J Struct Chem 53, 138–144 (2012). https://doi.org/10.1134/S0022476612010180
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DOI: https://doi.org/10.1134/S0022476612010180