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Crystal structures of rhodium(III) aqua ion with tetrahedral anions

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Abstract

The crystal structures of compounds of the composition [Rh(H2O)6]2(SO4)3·5H2O (I) and [Rh(H2O)6]PO4 (II) are determined. Crystallographic data for I: a = 7.272(9) Å, b = 27.047(1) Å, c = 12.464(9) Å, β = 97.038(10)°, P21 space group, Z = 4, d x = 2.184 g/cm3; for II: a = 9.746(6)Å, b = 6.877(7) Å, c = 23.623(6) Å, β = 100.601(10)°, C2/c space group, Z = 8, d x = 2.611 g/cm3. Compounds are analyzed by IR spectroscopy and powder XRD. Crystalline phase I is well soluble in water, whereas II is almost insoluble.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    S. N. Vorob’eva, I. A. Baidina, A. V. Belyaev & N. I. Alferova

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  1. S. N. Vorob’eva
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  2. I. A. Baidina
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  3. A. V. Belyaev
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  4. N. I. Alferova
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Corresponding author

Correspondence to I. A. Baidina.

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Original Russian Text Copyright © 2012 by S. N. Vorob’eva, I. A. Baidina, A. V. Belyaev, and N. I. Alferova

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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 1, pp. 130–136, January–February, 2012.

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Vorob’eva, S.N., Baidina, I.A., Belyaev, A.V. et al. Crystal structures of rhodium(III) aqua ion with tetrahedral anions. J Struct Chem 53, 125–131 (2012). https://doi.org/10.1134/S0022476612010167

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  • DOI: https://doi.org/10.1134/S0022476612010167

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