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Analysis of pair heterovalent substitutions in scheelite-type molybdates and tungstates

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Abstract

An analysis of the formation of solid solutions in MAO4-(Me0.5Ln0.5)AO4 systems, where Me = Li, Na, K; M = Ca, Sr, Ba, Pb, Cd; Ln = La-Gd, Y, Bi; A = Mo, W, is performed in the approximation of regular solutions. Equations that make it possible to determine the temperature of the transition of limited solid solutions to unlimited ones at heterovalent substitutions M2+ ↔ (Me +0.5 Ln 3+0.5 ) are obtained.

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References

  1. J.A. Groenink and G. J. Blasse, J. Sol. State Chem., 32, No. 1, 9 (1980).

    Article  CAS  Google Scholar 

  2. V. Babin, P. Bohachek, A. Krasnikov, et al., J. Luminescence, 124, No. 1, 113 (2007).

    Article  CAS  Google Scholar 

  3. Zhengliang Wang, Hongbin Liang, Jing Wang, et al., Mater. Res. Bul., 43, No. 1, 907 (2008).

    Article  CAS  Google Scholar 

  4. L. Zhen, W. S. Wang, C. Y. Xu, et al., Scripta Mater., 58, 461 (2008).

    Article  CAS  Google Scholar 

  5. Zb. Mazurak and G. Blasse, J. Solid State Chem., 68, 181 (1987).

    Article  CAS  Google Scholar 

  6. Zhengliang Wang, Hongbin Liang, Liya Zhou, et al., Chem. Phys. Lett., 412, Nos. 4–6, 313 (2005).

    Article  CAS  Google Scholar 

  7. Kyoung Ho Lee, Ki-Woong Chae, Chae Il Cheon, and Jeong Seog Kim, J. Europ. Ceram. Soc., 30, No. 2, 243 (2010).

    Article  CAS  Google Scholar 

  8. V. M. Longo, E. Orhan, L. S. Cavallcante, et al., Chem. Phys., 334, Nos. 1–3, 180 (2007).

    Article  CAS  Google Scholar 

  9. Shikao Shi, Jing Gao, and Ji Zhou, Optical Mater., 30, No. 10, 1616 (2008).

    Article  CAS  Google Scholar 

  10. Liya Zhou, Jianshe Wei, Jingrong Wu, et al., J. Alloys Comp., 476, Nos. 1/2, 390 (2009).

    Article  CAS  Google Scholar 

  11. Jun Gu, Yongchun Zhu, Haibo Li, et al., J. Solid State Chem., 183, No. 3, 497 (2010).

    Article  CAS  Google Scholar 

  12. V. S. Urusov, Theory of Isomorphic Miscibility [in Russian], Nauka, Moscow (1977).

    Google Scholar 

  13. V. K. Trunov, V. A. Efremov, and Yu. A. Velikodnyi, Crystal Chemistry and Properties of Binary Molybdates and Tungstates [in Russian], Nauka, Leningrad (1986).

    Google Scholar 

  14. V. D. Zhuravlev, T. A. Patrusheva, O. G. Reznitskikh, and N. D. Koryakin, Zh. Neorg. Khim., 54, No. 9, 1 (2009).

    Google Scholar 

  15. ICDD PDF2 (ICDD, USF, Release 2005)

  16. V. D. Zhuravlev, Izv. Ross. Akad. Nauk, Ser. Fiz., 71, No. 5, 705 (2007).

    CAS  Google Scholar 

  17. V. D. Zhuravlev, M. Ya. Khodos, and Yu. A. Velikodnyi, Zh. Neorg. Khim., 37, No. 3, 535 (1992).

    CAS  Google Scholar 

  18. E. I. Get’man, Isomorphic Substitutions in Tungstate and Molybdate Systems [in Russian], Nauka, Novosibirsk (1985).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg, Russia

    V. D. Zhuravlev & O. G. Reznitskikh

Authors
  1. V. D. Zhuravlev
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  2. O. G. Reznitskikh
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Correspondence to V. D. Zhuravlev.

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Original Russian Text Copyright © 2012 by V. D. Zhuravlev and O. G. Reznitskikh

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Translated from Zhurnal Strukturnoi Khimii, Vol. 53, No. 1, pp. 105–109, January–February, 2012.

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Zhuravlev, V.D., Reznitskikh, O.G. Analysis of pair heterovalent substitutions in scheelite-type molybdates and tungstates. J Struct Chem 53, 100–104 (2012). https://doi.org/10.1134/S002247661201012X

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  • DOI: https://doi.org/10.1134/S002247661201012X

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