Skip to main content
SpringerLink
Log in

Relaxation processes of the structural rearrangement of clusters in liquids: 1,2-ethanediol, 1,2-propanediol, and 1,2,6-hexanetriol

  • Proceedings of the 15th Symposium on Intermolecular Interactions and Conformations of Molecules Petrozavodsk, 2010, June 14–18
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The dielectric relaxation spectra (DRS) of 1,2-ethanediol, 1,2-propanediol, and 1,2,6-gexanetriol are analyzed in terms of the Dissado-Hill (DH) model in a wide range of temperatures, with all parameters required for calculating the cluster dipole moments being determined within the DH molecular model itself. The dependence of the equilibrium and relaxation properties of DRS on the hydrocarbon radical length and the number of OH groups is studied. The dipole moments of the clusters are calculated. It is shown how the roles of the processes of intracluster rearrangement are redistributed due to the break of hydrogen bonds and fluctuation processes of synchronous exchange of molecules between the clusters.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. H. Frölich, Theory of Dielectrics, Clarendon press, Oxford (1958).

    Google Scholar 

  2. M. I. Shakhparonov, Mechanisms of Fast Processes in Liquids [in Russian], Vysshaya Shkola, Moscow (1980).

    Google Scholar 

  3. V. I. Zhuravlev, O. V. Grineva, N. V. Lifanova, and T. M. Usacheva, Zh. Fiz. Khim., 71, No. 12, 2282–2285 (1997).

    CAS  Google Scholar 

  4. V. I. Zhuravlev, T. M. Usacheva, and N. V. Lifanova, Zh. Fiz. Khim., 72, No. 4, 637–643 (1998).

    CAS  Google Scholar 

  5. V. I. Zhuravlev, N. V. Lifanova, and T. M. Usacheva, J. Mol. Liq., 120, 107–110 (2005).

    Article  CAS  Google Scholar 

  6. T. M. Usacheva, N. V. Lifanova, V. I. Zhuravlev, et al., Zh. Fiz. Khim., 75, No. 7, 1258–1262 (2001).

    CAS  Google Scholar 

  7. N. V. Lifanova, T. M. Usacheva, V. I. Zhuravlev, and V. K. Matveev, J. Phys. Chem., 81, No. 5, 820–828 (2007).

    CAS  Google Scholar 

  8. N. V. Lifanova, T. M. Usacheva, V. I. Zhuravlev, and V. K. Matveev, J. Phys. Chem., 82, No. 10, 1769–1777 (2008).

    CAS  Google Scholar 

  9. T. M. Usacheva, N. V. Lifanova, V. I. Zhuravlev, and V. K. Matveev, J. Phys. Chem., 84, No. 7, 1194–1201 (2010).

    CAS  Google Scholar 

  10. V. A. Durov and I. Y. Shilov, J. Mol. Liq., 136, 300–309 (2007).

    Article  CAS  Google Scholar 

  11. L. A. Dissado and R. M. Hill, Nature, 279, 685–689 (1979).

    Article  CAS  Google Scholar 

  12. L. A. Dissado and R. M. Hill, Philos. Mag. Part B, 41, No. 6, 625–642 (1980).

    Article  CAS  Google Scholar 

  13. L. A. Dissado and R. M. Hill, J. Chem. Soc. Faraday Trans. II, 78, No. 1, 81–93 (1982).

    Article  CAS  Google Scholar 

  14. L. A. Dissado and R. M. Hill, Proc. R. Soc. Lond. A, 390, 131–180 (1983).

    Article  CAS  Google Scholar 

  15. R. M. Hill and L. A. Dissado, J. Phys. C: Solid State Phys., 15, No. 25, 5171–5193 (1982).

    Article  CAS  Google Scholar 

  16. R. M. Hill, Phys. Status Solidi B, 103, No. 1, 319–328 (1981).

    Article  CAS  Google Scholar 

  17. S. Havriliak and S. Negami, Polymer, 8, No. 8, 161–210 (1967).

    Article  CAS  Google Scholar 

  18. J. Li. Tamarit, M. A. Perez-Jubindo, and M. R. Fuente, J. Phys.: Condens. Matter., 9, 5469–5478 (1997).

    Article  CAS  Google Scholar 

  19. H. Forsman, P. Andersson, and G. Bäckström, J. Chem. Soc. Faraday. Trans. II, 82, 857–868 (1986).

    Article  CAS  Google Scholar 

  20. H. Forsman, Mol. Phys., 63, 65–75 (1988).

    Article  CAS  Google Scholar 

  21. H. Forsman, J. Phys. D.: Appl. Phys., 22, 1528–1536 (1989).

    Article  CAS  Google Scholar 

  22. T. M. Usacheva, N. V. Lifanova, V. I. Zhuravlev, and V.K. Matveev, J. Struct. Chem., 50, No. 5, 930–942 (2009).

    Article  CAS  Google Scholar 

  23. T. M. Usacheva, N. V. Lifanova, V. I. Zhuravlev, and V. K. Matveev, J. Phys. Chem., 76, No. 12, 1956–1961 (2002).

    Google Scholar 

  24. F. J. Lovas, D. F. Plusquellic, B. H. Pate, et al., J. Mol. Spectroscop., 257, No. 1, 82–93 (2009).

    Article  CAS  Google Scholar 

  25. S. Vázquez, R. A. Mosquera, M. A. Rio, and C. V. Alsenoy, J. Mol. Struct. (Theochem.), 184, 323–342 (1989).

    Article  Google Scholar 

  26. W. Caminati, J. Mol. Spectroscop., 86, 193–201 (1981).

    Article  CAS  Google Scholar 

  27. T. J. L. Lockley, P. I. Hearn, A. K. King, and B. J. Howard, J. Mol. Struct., 612, 199–206 (2002).

    Article  CAS  Google Scholar 

  28. O. A. Osipov, V. I. Minkin, and A. D. Granovskii, Handbook of Dipole Moments [in Russian], Vysshaya Shkola, Moscow (1971).

    Google Scholar 

  29. J. D. Ferry, Viscoelastic Properties of Polymers, New York (1961).

  30. Th. Dorfműler, H. Dux, G. Fytas, and W. Mersch, J. Chem. Phys., 71, No. 1, 366–375 (1971).

    Article  Google Scholar 

  31. N. Fransson and G. Backstrom, Mol. Phys., 61, No. 1, 131–141 (1987).

    Article  CAS  Google Scholar 

  32. F. Daniels and R. Alberti, Physical Chemistry, John Wiley and Sons, New York (4th edition, 1975).

    Google Scholar 

  33. G. Adam and J. H. Gibbs, J. Chem. Phys., 43, No. 1, 139–146 (1965).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Faculty of Chemistry, M. V. Lomonosov Moscow State University, Moscow, Russia

    T. M. Usacheva, V. I. Zhuravlev, N. V. Lifanova & V. K. Matveev

Authors
  1. T. M. Usacheva
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. I. Zhuravlev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. V. Lifanova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. K. Matveev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to V. I. Zhuravlev.

Additional information

Original Russian Text Copyright © 2011 by T. M. Usacheva, V. I. Zhuravlev, N. V. Lifanova, and V. K. Matveev

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 6, pp. 1189–1196, November–December, 2011.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Usacheva, T.M., Zhuravlev, V.I., Lifanova, N.V. et al. Relaxation processes of the structural rearrangement of clusters in liquids: 1,2-ethanediol, 1,2-propanediol, and 1,2,6-hexanetriol. J Struct Chem 52, 1153–1160 (2011). https://doi.org/10.1134/S0022476611060217

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476611060217

Keywords

Search

Navigation