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Structure of a new molecular rhenium cluster complex: trans-{[Ni(NH3)5]2×[Re6Se8(CN)4(OH)2]}·6H2O

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Abstract

Counter-diffusion of the aqueous solution of Cs2.75K1.25[Re6Se8(CN)4(OH)2] and a water-ammonia solution of NiCl2 afforded crystals of a rhenium cluster complex trans-{[Ni(NH3)5]2[Re6Se8(CN)4(OH)2]}·6H2O. The structure of the complex is determined by single crystal X-ray diffraction. In the structure, nickel atoms have an octahedral coordination environment involving nitrogen atoms of five NH3 ligands and one CN ligand of the cluster anion. The anion has two bridging CN ligands in the trans-positions

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Ermolaev, A. I. Smolentsev & Yu. V. Mironov

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  1. A. V. Ermolaev
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  2. A. I. Smolentsev
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  3. Yu. V. Mironov
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Correspondence to Yu. V. Mironov.

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Original Russian Text Copyright © 2011 by A. V. Ermolaev, A. I. Smolentsev, and Yu. V. Mironov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 6, pp. 1161–1163, November–December, 2011.

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Ermolaev, A.V., Smolentsev, A.I. & Mironov, Y.V. Structure of a new molecular rhenium cluster complex: trans-{[Ni(NH3)5]2×[Re6Se8(CN)4(OH)2]}·6H2O. J Struct Chem 52, 1124–1126 (2011). https://doi.org/10.1134/S0022476611060151

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  • DOI: https://doi.org/10.1134/S0022476611060151

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