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Crystal structure of a complex of nickel(II) with 2-amino-4-imino-2-pentene

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Abstract

The structure of a nickel(II) complex with 2-amino-4-iminopentane is determined by X-ray crystallography at 150 K. Crystal data for C10H18N4Ni are: a = 10.9802(3)Å, b = 13.5780(4)Å, c = 8.0935(2)Å, β = 107.304(1)°, space group P21/c, V = 1152.04(5) Å3, Z = 4, d x = 1.459 g/cm3, R = 0.0283. The structure is molecular; the metal atom is coordinated by four nitrogen atoms of two β-diimine ligands. The Ni-N distances in Ni(NacNac)2 fall within 1.8571–1.8623 Å. The molecules in the crystal are joined by only van der Waals interactions.

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References

  1. T. Maruyama and T. Tago, J. Mater. Sci., 28, 5345–5349 (1993).

    Article  CAS  Google Scholar 

  2. J. Crofton, P. G. McMillan, J. R. Williams, and M. J. Bozack, J. Appl. Phys., 77, 1317–1324 (1995).

    Article  CAS  Google Scholar 

  3. M. W. Cole, C. Hubbard, C. G. Fountzoulas, et al, Electrochem. Solid State Lett., 2, 97–116 (1999).

    Article  CAS  Google Scholar 

  4. L. Brissonneau and C. Vahlas, Ann. Chim. Sci. Mater., 25, 81–87 (2000).

    Article  CAS  Google Scholar 

  5. P. Karvankova, H. D. Mannling, C. Eggs, and S. Veprek, Surf. Coat. Technol., 280, 146–151 (2001).

    Google Scholar 

  6. F. B. Wu, J. J. Li, and J. G. Duh, Thin Solid Films, 354, 377/378 (2000).

    Google Scholar 

  7. F. Caturla, F. Molina, M. Sabio, and F. Rodriguez, J. Electrochem. Soc., 142, 4084–4086 (1995).

    Article  CAS  Google Scholar 

  8. M. R. Leonov, V. A. Ilyushenkov, and N. I. Kiselev, Radiochemistry, 39, 239 (1997).

    CAS  Google Scholar 

  9. S. Arockiasamy, C. Mallika, O. M. Sreetharan, et al, Inorgan. Chim. Acta, 362, 1977–1983 (2009).

    Article  CAS  Google Scholar 

  10. S. Arockiasamya, O. M. Sreedharana, C. Mallika, et al, Chem. Engineering Sci., 62, 1703–1711 (2007).

    Article  Google Scholar 

  11. E. Lindahl, M. Ottosson, and J.-O. Carlson, ECS Transactions, 25, No. 8, 365–372 (2009).

    Article  CAS  Google Scholar 

  12. A. C. Jones and M. L. Hitchman (eds.), in: Chemical Vapour Deposition: Precursors, Processes and Applications, Royal Society of Chemistry, London (2009).

    Google Scholar 

  13. N. Alam, M. S. Hill, G. Kociok-Köhn, et al, Mater., 20, 6157–6162 (2008).

    CAS  Google Scholar 

  14. J. Cheon, D. S. Talaga, and J. I. Zink, Chem. Mater., 9, 1208–1212 (1997).

    Article  CAS  Google Scholar 

  15. P. A. Stabnikov, G. I. Zharkova, I. A. Baidina, et al, Polyhedron, 26, 4445–4450 (2007).

    Article  CAS  Google Scholar 

  16. S. G. McGeachin, Can. J. Chem., 46, 1903–1912 (1968).

    Article  CAS  Google Scholar 

  17. N. B. Morozova, P. A. Stabnikov, and I.A. Baidina, J. Struct. Chem, 48, 889–898 (2007).

    Article  CAS  Google Scholar 

  18. Bruker AXS Inc. (2004). APEX2 (Version 1.08), SAINT (Version 7.03), and SADABS (Version 2.11). Bruker Advanced X-ray Solutions, Madison, Wisconsin, USA.

    Google Scholar 

  19. G. M. Sheldrick, Acta Crystallogr., 64, No. 1, 112–122 (2008).

    Article  Google Scholar 

  20. P. C. Healy, M. R. Bendall, D. M. Doddrell, et al, Aust. J. Chem., 32, 727–731 (1979).

    Article  CAS  Google Scholar 

  21. P. B. Hitchcock, M. F. Lappert, M. Linnolahti, et al, J. Organomet. Chem., 694, 667–672 (2009).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    S. I. Dorovskikh, K. V. Zherikova, N. V. Kuratieva & N. B. Morozova

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  1. S. I. Dorovskikh
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  2. K. V. Zherikova
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  3. N. V. Kuratieva
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  4. N. B. Morozova
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Correspondence to S. I. Dorovskikh.

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Original Russian Text Copyright © 2011 by S. I. Dorovskikh, K. V. Zherikova, N. V. Kuratieva, and N. B. Morozova

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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 6, pp. 1157–1160, November–December, 2011.

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Dorovskikh, S.I., Zherikova, K.V., Kuratieva, N.V. et al. Crystal structure of a complex of nickel(II) with 2-amino-4-imino-2-pentene. J Struct Chem 52, 1120–1123 (2011). https://doi.org/10.1134/S002247661106014X

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  • DOI: https://doi.org/10.1134/S002247661106014X

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