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Crystal structures of two new dinuclear Ag(I) complexes constructed from 4,4′-biphenyldicarboxylic acid and N-containing ligands

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Abstract

The reaction of silver 4,4′-biphenyldicarboxylate with 1,3-diaminopropane (DAP) and 2-amino-5-methylpyridine (AMP) respectively results in the formation of two dinuclear silver(I) complexes: [Ag2(DAP)2](BPC)·2H2O (1) and [Ag2(BPC)(AMP)4]·2H2O (2), where BPC is 4,4′-biphenyldicarboxylate. The complexes are characterized by elemental analysis and X-ray crystallography. Complex 1 crystallizes in the triclinic system, P-1 space group, a = 8.585(2) Å, b = 8.849(2) Å, c = 9.890(3) Å, α = 107.893(3)°, β = 94.139(3)°, γ = 113.202(3)°, V = 640.9(3) Å3, Z = 1. Complex 2 crystallizes in the triclinic system, P-1 space group, a = 11.818(3) Å, b = 13.132(4) Å, c = 13.281(4) Å, α = 92.571(4)°, β = 96.425(3)°, γ = 102.142(4)°, V = 1997.5(10) Å3, Z = 2. Complex 1 consists of a macrocyclic dinuclear silver(I) dication, a 4,4′-biphenyldicarboxylate anion, and two water molecules of crystallization. Each Ag atom is in a linear coordination. Complex 2 consists of a dinuclear silver(I) complex molecule and two water molecules of crystallization. Each Ag atom is in a T-shaped coordination. The Ag...Ag separations are 5.127(2) Å in 1 and 3.172(2) Å in 2.

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References

  1. D.-X. Xue, Y.-Y. Lin, X.-N. Cheng, et al., Cryst. Growth Des., 7, 1332 (2007).

    Article  CAS  Google Scholar 

  2. C.-M. Liu, S. Gao, D.-Q. Zhang, et al., Cryst. Growth Des., 7, 1312 (2007).

    Article  CAS  Google Scholar 

  3. X. Chen, P. Yang, S.-L. Ma, et al., J. Struct. Chem., 50, No. 3, 495–499 (2009).

    Article  CAS  Google Scholar 

  4. Y.-B. Dong, L. Wang, J.-P. Ma, et al., Cryst. Growth Des., 6, 2475 (2006).

    Article  CAS  Google Scholar 

  5. E. C. Plappert, D. M. P. Mingos, S. E. Lawrence, et al., J. Chem. Soc., Dalton Trans., 2119 (1997).

  6. K. Cheng, H.-L. Zhu, and Y.-G. Li, Z. Anorg. Allg. Chem., 632, 2326 (2006).

    Article  Google Scholar 

  7. S. Q. Liu, H. Konaka, T. Kuroda-Sowa, et al., Inorg. Chim. Acta, 358, 919 (2005).

    Article  CAS  Google Scholar 

  8. H. Lang, M. Leschke, G. Rheinwald, et al., Inorg. Chem. Commun., 1, 254 (1998).

    Article  CAS  Google Scholar 

  9. O. Kristiansson, Cryst. Growth Des., 40, 5058 (2001).

    CAS  Google Scholar 

  10. G. M. Sheldrick, Acta Crystallogr., A64, 112 (2008).

    CAS  Google Scholar 

  11. G. M. Sheldrick, SADABS, v. 2.03, Bruker/Siemens Area Detector Absorption Correction Program, Bruker AXS, Madison, Wisconsin, USA (2003).

    Google Scholar 

  12. C.-X. Ren, H.-L. Zhu, G. Yang, et al., J. Chem. Soc., Dalton Trans., 85 (2001).

  13. A. L. Pickering, G. J. T. Cooper, D.-L. Long, et al., Polyhedron, 23, 2075 (2004).

    Article  CAS  Google Scholar 

  14. M. Sarkar and K. Biradha, Crys. Eng. Comm., 6, 310 (2004).

    CAS  Google Scholar 

  15. Z.-L. You, H.-L. Zhu, and W.-S. Liu, Acta Crystallogr., E60, m1863 (2004).

    CAS  Google Scholar 

  16. S. Smith, A. N. Reddy, K. A. Byriel, et al., J. Chem. Soc., Dalton Trans., 3565 (1995).

  17. S. Smith, B. A. Cloutt, D. E. Lynch, et al., Inorg. Chem., 37, 3236 (1998).

    Article  CAS  Google Scholar 

  18. H.-L. Zhu, A. Usman, H.-K. Fun, et al., Acta Crystallogr., C59, m 218 (2003).

    CAS  Google Scholar 

  19. H.-L. Zhu, X.-Y. Liu, X.-J. Wang, et al., Z. Anorg. Allg. Chem., 629, 1986 (2003).

    Article  Google Scholar 

  20. A. L. Spek, Acta Crystallogr., D65, 148 (2009).

    CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. Department of Public Subject, Shangqiu Medical College, Shangqiu, 476000, PR China

    S. -F. Lou

  2. Department of Chemisry, Shangqiu Normal University, Shangqiu, 476000, PR China

    X. Zheng, Y. Chen & X. -Y. Qiu

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  1. S. -F. Lou
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  2. X. Zheng
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  3. Y. Chen
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  4. X. -Y. Qiu
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Correspondence to S. -F. Lou.

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Original Russian Text Copyright © 2011 by S.-F. Lou, X. Zheng, Y. Chen, and X.-Y. Qiu

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 52, No. 6, pp. 1129–1135, November–December, 2011.

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Lou, S.F., Zheng, X., Chen, Y. et al. Crystal structures of two new dinuclear Ag(I) complexes constructed from 4,4′-biphenyldicarboxylic acid and N-containing ligands. J Struct Chem 52, 1091–1097 (2011). https://doi.org/10.1134/S0022476611060084

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  • DOI: https://doi.org/10.1134/S0022476611060084

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