Skip to main content
SpringerLink
Log in

Study of the structure of a new heterometallic complex based on copper(II) ketoiminate [cis-Cu(ki)2·Pb(hfa)2]2

  • Brief Communications
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

The cocrystallization method is used to obtain a new volatile heterometallic complex of the composition [Cu(ki)2·Pb(hfa)2]2, where ki = 2-iminopentan-4-onate and hfa = hexafluoroacetylacetonate. The crystallographic data for C20H18CuF12N2O6Pb: a = 10.6729(5)Å, b = 10.7712(5)Å., c = 13.4779(5)Å.; α = 79.1020(10)°, β = 84.5140(10)°, γ = 66.2470(10)°, P-1 space group, Z = 2, d x = 2.102 g/cm3. The compound has a molecular structure built of individual Cu...Pb...Pb...Cu-type tetramers. The Cu...Pb and Pb...Pb distances in the tetramer are 3.454. and 4.122. respectively; the Cu-Pb-Pb angle is 160.7°.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. I. A. Baidina, V. V. Krisyuk, and P. A. Stabnikov, J. Struct. Chem., 47,No. 6, 1111–1116 (2006).

    Article  CAS  Google Scholar 

  2. I. A. Baidina, V. V. Krisyuk, E. V. Peresypkina, and P. A. Stabnikov, J. Struct. Chem., 49,No. 2, 304–308 (2008).

    Article  CAS  Google Scholar 

  3. I. A. Baidina, V. V. Krisyuk, E. V. Peresypkina, and P. A. Stabnikov, J. Struct. Chem., 49,No. 3, 489–493 (2008).

    Article  CAS  Google Scholar 

  4. C. H. Sheldrick, SHELX-97, Release 97-1, Univ. G.ttingen, Germany (1997).

    Google Scholar 

  5. P. A. Stabnikov, I. A. Baidina, S. V. Sysoev, et al., J. Struct. Chem., 44,No. 6, 1054–1061 (2003).

    Article  CAS  Google Scholar 

  6. V. V. Krisyuk, I. A. Baidina, and I. K. Igumenov, Main Group Metal Chemistry, 21,No. 4, 199–206 (1998).

    Article  CAS  Google Scholar 

  7. I. A. Baidina, V. V. Krisyuk, and P. A. Stabnikov, Self-Assembled Supramolecular Structures Based on Lead and Copper Beta-Diketonates, MOLMAT Proceedings, Toulouse, France (2008), p. 213.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    I. A. Baidina, V. V. Krisyuk, I. V. Korol’kov & P. A. Stabnikov

Authors
  1. I. A. Baidina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. V. Krisyuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. V. Korol’kov
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. P. A. Stabnikov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. A. Baidina.

Additional information

Original Russian Text Copyright © 2011 by I. A. Baidina, V. V. Krisyuk, I. V. Korol’kov, and P. A. Stabnikov

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 5, pp. 1034–1037, September–October, 2011.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Baidina, I.A., Krisyuk, V.V., Korol’kov, I.V. et al. Study of the structure of a new heterometallic complex based on copper(II) ketoiminate [cis-Cu(ki)2·Pb(hfa)2]2 . J Struct Chem 52, 1008–1011 (2011). https://doi.org/10.1134/S0022476611050283

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476611050283

Keywords

Search

Navigation