Skip to main content
SpringerLink
Log in

Crystal structure and activity of a new Cu(II) complex with O...Cu weak interaction

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

A new CuL2 (HL = α-hydroxyacetophenone) complex is synthesized and investigated by elemental analysis, IR, UV-Vis, and X-ray diffraction. The complex crystallizes in the orthorhombic space group Pbca, a = 14.595(3) Å, b = 12.517(3) Å, c = 15.474(3)Å, V = 2826.88(1) Å3, Z = 4. The title complex has a square-planar geometry around the central Cu2+ ion. Two molecules form a dimer via a weak Cu1...O3 interaction, and the neighboring dimers of molecules are connected into a 2D structure through two very weak C-H...O interactions. The title complexes has high activity of killing pine wood nematodes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. Xu, Y. Kim, and S. Kim, Acta Crystallogr., E61, o3344/o3345 (2005).

    Google Scholar 

  2. J. H. Weber, Inorg. Chem., 6, 258 (1967).

    Article  CAS  Google Scholar 

  3. N. J. Long, Angew. Chem. Int. Ed. Eng., 34, 21 (1995).

    Article  CAS  Google Scholar 

  4. L. Xu, X. T. Chen, Y. Xu, et al., J. Mol. Struct., 559, 361 (2001).

    Article  CAS  Google Scholar 

  5. M. R. Bermejo, A. M. González-Noya, V. Abad, et al., Eur. J. Inorg. Chem., 3696 (2004).

  6. H.-Z. Kou, Z.-H. Ni, B. C. Zhou, and R.-J. Wang, Inorg. Chem. Commun., 7, 1150 (2004).

    Article  CAS  Google Scholar 

  7. S. Majumder, P. Dutta, A. Mookerjee, and S. K. Choudhuri, Chemico-Biological Interactions, 159, 90 (2006).

    Article  CAS  Google Scholar 

  8. D. Dakternieks, T. S. B. Baul, S. Dutta, and E. R. T. Tiekink, Organometallics, 17, 3058 (1998).

    Article  CAS  Google Scholar 

  9. Bruker SMART and SAINT, Bruker AXS Inc., Madison, Wisconsin, USA (1997).

  10. Bruker SHELXTL, Version 5.10, Bruker AXS Inc., Madison, Wisconsin, USA (1998).

  11. L. Xu, Y. Z. Li, S. H. Liu, et al., Acta Crystallogr., E61, m364 (2005).

    CAS  Google Scholar 

  12. A. El-Jammal, P. L. Howell, M. A. Turner, et al., J. Med. Chem., 37, 461 (1994).

    Article  CAS  Google Scholar 

  13. S. S. Batsanov, Russ. J. Inorg. Chem., 36, 1694 (1991).

    Google Scholar 

  14. S. S. Batsanov, Inorg. Mater., 37, 871 (2001).

    Article  CAS  Google Scholar 

  15. T. H. Li, J. Lü, S. Y. Gao, and R. Cao, Inorg. Chem. Commun., 10, 551 (2007).

    Article  CAS  Google Scholar 

  16. A. Tian, Z. Han, J. Peng, et al., Inorg. Chim. Acta, 361, 1332 (2008).

    Article  CAS  Google Scholar 

  17. J. P. Cheng, Q. Y. Lin, W. Z. Zhu, and R. D. Wang, Acta Chim. Sinica, 66(23), 2597 (2008).

    CAS  Google Scholar 

  18. X. N. Dong, Y. C. Zhu, Y. H. Guo, and G. Q. Chang, J. Tianshui Normal Univ., 26, 34 (2006).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Science, Nanjing Forestry University, Nanjing, China, 2 10037

    W. Wang, X. Zhou & L. Xu

  2. Department of Chemistry and Materials Engineering, Changsu Institute of Technology, Changsu, China

    Y. -S. Ma & R. -X. Yuan

  3. College of Forest Resources and Environment, Nanjing Forestry University, Nanjing, China

    Z. -C. Zhang & B. -G. Zhao

  4. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, China

    L. Xu

Authors
  1. W. Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. X. Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Y. -S. Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Z. -C. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. R. -X. Yuan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. B. -G. Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. L. Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. Xu.

Additional information

Original Russian Text Copyright © 2011 by W. Wang, X. Zhou, Y.-S. Ma, Z.-C. Zhang, R.-X. Yuan, B.-G. Zhao, and L. Xu

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 52, No. 4, pp. 802–805, July–August, 2011.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, W., Zhou, X., Ma, Y.S. et al. Crystal structure and activity of a new Cu(II) complex with O...Cu weak interaction. J Struct Chem 52, 781–784 (2011). https://doi.org/10.1134/S0022476611040214

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476611040214

Keywords

Search

Navigation