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X-ray diffraction study of crystal and molecular structure of acetylacetone azocompound — [C11H11N2O2F1]

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Abstract

The 3-[4-fluorophenylazopentandion]-2,4 reagent is synthesized based on acetylacetone, and its crystal and molecular structure is studied by X-ray diffraction. It is found that [C11H11N2O2F] crystals 1 belong to the monoclinic symmetry, C2/c space group. The unit cell parameters of 1 are a = 18.827(3) Å, b = 12.839(2) Å, c = 26.475(5) Å, β = 104.834(2)°. The analysis shows that the reagent is present in the solution as well as in the crystal. A comparative analysis of these three structures with the reported data is carried out.

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Authors and Affiliations

  1. Faculty of Chemical Sciences, Baku State University, Baku, Azerbaijan

    M. A. Magerramov, R. A. Alieva & F. M. Chyragov

  2. Vladimir State University for the Humanities, Vladimir, Russia

    R. Z. Nazarova & K. A. Potekhin

Authors
  1. M. A. Magerramov
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  2. R. A. Alieva
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  3. R. Z. Nazarova
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  4. F. M. Chyragov
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  5. K. A. Potekhin
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Corresponding author

Correspondence to R. Z. Nazarova.

Additional information

Original Russian Text Copyright © 2011 by M. A. Magerramov, R. A. Alieva, R. Z. Nazarova, F. M. Chyragov, and K. A. Potekhin

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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 1, pp. 201–205, January–February, 2011.

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Magerramov, M.A., Alieva, R.A., Nazarova, R.Z. et al. X-ray diffraction study of crystal and molecular structure of acetylacetone azocompound — [C11H11N2O2F1]. J Struct Chem 52, 198–202 (2011). https://doi.org/10.1134/S0022476611010276

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  • DOI: https://doi.org/10.1134/S0022476611010276

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