Abstract
The structure of aluminum(III) tris-dipivaloylmethanate (Bruker Nonius X8 Apex diffractometer with a 4K CCD detector, λMoK α, graphite monochromator, T = 150(2) K) is determined, and the synthetic procedure for its preparation is suggested. Crystal data are: C2/c space group, a = 28.1587(12) Å, b = 18.5170(7) Å, c = 21.5332(8) Å, β = 97.573(1)°, V = 11129.8(8) Å3, Z = 12, d x = 1.033 g/cm3, R = 6.93. The complex has a molecular structure; the aluminum atom is octahedrally surrounded by six oxygen atoms of three chelating ligands; Al-O distances are 1.860(2)–1.873(2)0A; O-Al-O angles fall within 88.08(9)–91.96(10)° and 177.93(9)–179.83(14)°. The known crystal packings of metal tris-dipivaloylmethanates are analyzed. Three types of the arrangement of the molecules in the crystals denoted as α, β, and γ are identified.
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Original Russian Text Copyright © 2011 by P. A. Stabnikov, A. I. Smolentsev, N. V. Pervukhina, O. S. Koshcheeva, L. N. Komissarova, and S. V. Borisov
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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 1, pp. 122–128, January–February, 2011.
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Stabnikov, P.A., Smolentsev, A.I., Pervukhina, N.V. et al. Structure of aluminum(III) dipivaloylmethanate AlO6C33H57 . J Struct Chem 52, 118–124 (2011). https://doi.org/10.1134/S0022476611010161
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DOI: https://doi.org/10.1134/S0022476611010161