Abstract
Iron(III)-containing complexes with an asymmetric tridentate azomethine 4,4′-dodecyloxybenzoyloxybenzoyl-4-salicylidene-N′-ethyl-N-ethylenediamine ligand with NO −3 , PF −6 , Cl−, and BF −4 counterions are synthesized. The presence of the complexation ion is confirmed by the far FTIR spectra. The structure of the compounds is determined by the matrix-assisted laser desorption/ionizationtime of flight (MALDI-ToF) method. The results of mass-spectrometric studies are consistent with the elemental analysis data. The complexation of iron salts with the asymmetric tridentate ligand is found to yield compounds of the 1:1 composition with octahedral packing of iron in the complex.
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Original Russian Text Copyright © 2011 by M. S. Gruzdev, U. V. Chervonova, A. M. Kolker, and N. E. Domracheva
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Translated from Zhurnal Strukturnoi Khimii, Vol. 52, No. 1, pp. 88–95, January–February, 2011.
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Gruzdev, M.S., Chervonova, U.V., Kolker, A.M. et al. Structure of Iron(III)-containing complexes based on the azomethine — 4,4′-dodecyloxy-benzoyloxybenzoyl-4-salicylidene-N′-Ethyl-N-ethylenediamine molecule. J Struct Chem 52, 83–90 (2011). https://doi.org/10.1134/S0022476611010112
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DOI: https://doi.org/10.1134/S0022476611010112