The shape of the coherent population trapping resonance in optically thin cells with antirelaxation coating of the walls has been determined by solving the quantum kinetic equation for the single-atom density matrix. It has been found that motion and collisions with walls in the case of nondegenerate ground and excited states result in a significant change in the shape of the spectrum, in the appearance of a comb of additional resonances, and in shifts of the main resonance of coherent population trapping, which nonmonotonically depend on the size of the cell.
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ACKNOWLEDGMENTS
The results of the work were obtained with the computer resources of the Supercomputer Center, Peter the Great St. Petersburg Polytechnic University (http://www.spbstu.ru).
Funding
This work was supported by the Ministry of Science and Higher Education of the Russian Federation (state assignment for basic research, theme no. FSEG-2020-0024).
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Litvinov, A.N., Sokolov, I.M. Effect of the Motion of Atoms and Collisions with the Antirelaxation Coating of the Walls of Gas Cells on the Shape and Shift of the Coherent Population Trapping Resonance. Jetp Lett. 113, 763–768 (2021). https://doi.org/10.1134/S0021364021120092
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DOI: https://doi.org/10.1134/S0021364021120092