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Raman Spectroscopy of Nanopolycrystalline Diamond Produced from Shungite at 15 GPa and 1600°C

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Abstract

It has been demonstrated that the high-pressure (15 GPa) treatment of shungite samples (Karelia, Russia) at a temperature of 1600°C for 2 h transforms them to diamond. The comparison of the Raman spectra of the diamond material prepared from shungite and carbonado, which is a rare variety of cubic diamond sometimes called black diamond, has revealed their significant similarities. Our data indicate the possible growth of carbonado from the shungite-like natural material, which may be one of the ways carbonado appears under terrestrial conditions.

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Funding

This work was supported by the Ministry of Science and Higher Education of the Russian Federation (state task for the Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences; Institute of Geology, Karelian Scientific Center, Russian Academy of Sciences; and Vereshchagin Institute for High Pressure Physics, Russian Academy of Sciences).

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Authors and Affiliations

  1. Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. P. Afanas’ev & S. V. Goryainov

  2. Vereshchagin Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk, Moscow, 108840, Russia

    K. D. Litasov

  3. Institute of Geology, Karelian Scientific Center, Russian Academy of Sciences, Petrozavodsk, 185610, Russia

    V. V. Kovalevskii

Authors
  1. V. P. Afanas’ev
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  2. K. D. Litasov
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  3. S. V. Goryainov
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  4. V. V. Kovalevskii
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Corresponding author

Correspondence to S. V. Goryainov.

Additional information

Russian Text © The Author(s), 2020, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2020, Vol. 111, No. 4, pp. 230–236.

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Afanas’ev, V.P., Litasov, K.D., Goryainov, S.V. et al. Raman Spectroscopy of Nanopolycrystalline Diamond Produced from Shungite at 15 GPa and 1600°C. Jetp Lett. 111, 218–224 (2020). https://doi.org/10.1134/S0021364020040050

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  • DOI: https://doi.org/10.1134/S0021364020040050

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