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Scaling Relations for Temperature Dependences of the Surface Self-Diffusion Coefficient in Crystallized Molecular Glasses

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Abstract

Crystallization kinetics has features that are universal and independent of the type of crystallized system. The possibility of using scaling relations to describe the temperature dependences of the surface self-diffusion coefficient Ds, which is one of the key characteristics of crystallization kinetics, has been demonstrated in application to various crystallized molecular glasses. It has been shown that the surface self-diffusion coefficient Ds as a function of the dimensionless temperature is reproduced by a power law and is universally scaled for all considered systems. The analysis of experimental data has revealed a correlation between the crystallization kinetic characteristics, index of fragility, and criterion of the glass-forming ability of a liquid. It has been shown that this correlation can be obtained within the generalized Einstein–Stokes relation.

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Acknowledgments

We are grateful to Prof. V.N. Ryzhov (Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk, Moscow) and Acad. V.V. Brazhkin (Institute for High Pressure Physics, Russian Academy of Sciences, Troitsk, Moscow) for valuable advice and discussions of some results of this work.

Funding

This work was supported by the Russian Science Foundation (project no. 19-12-00022).

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Authors and Affiliations

  1. Kazan Federal University, Kazan, 420008, Russia

    A. V. Mokshin, B. N. Galimzyanov & D. T. Yarullin

  2. Udmurt Research Center, Ural Branch, Russian Academy of Sciences, Izhevsk, 426067, Russia

    A. V. Mokshin & B. N. Galimzyanov

Authors
  1. A. V. Mokshin
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  2. B. N. Galimzyanov
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  3. D. T. Yarullin
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Corresponding authors

Correspondence to A. V. Mokshin, B. N. Galimzyanov or D. T. Yarullin.

Additional information

Russian Text © The Author(s), 2019, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2019, Vol. 110, No. 7, pp. 498–504.

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Mokshin, A.V., Galimzyanov, B.N. & Yarullin, D.T. Scaling Relations for Temperature Dependences of the Surface Self-Diffusion Coefficient in Crystallized Molecular Glasses. Jetp Lett. 110, 511–516 (2019). https://doi.org/10.1134/S002136401919010X

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  • DOI: https://doi.org/10.1134/S002136401919010X

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