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Photoinduced Migration of Ions in Optically Resonant Perovskite Nanoparticles

  • Optics And Laser Physics
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Abstract

Organic–inorganic perovskites with a mixed anion composition are widely used in solar cells, light-emitting diodes, and nanophotonic structures. Light nanosources based on resonant perovskite nanoparticles are of particular interest. However, perovskites with such a composition demonstrate the light-induced segregation of anions, which leads to a reversible dynamic rearrangement of the optical properties of a material and photoluminescence spectra. In this work, the photoinduced process of change in optical properties in resonant hybrid perovskite nanoparticles with a mixed anion composition (MAPbBr1.5I1.5, where MA = NH3CH +3 ) has been studied. Comparison with a similar process in a perovskite thin film with a similar composition has shown that the photoinduced migration of halogen ions in a nanoparticle occurs cyclically. This is due to the competition of two processes: the concentration of ions near the boundaries of the particle and migration caused by the gradient of the density of light-generated electron–hole pairs. This effect in resonant nanoparticles makes it possible to obtain optically tunable nanoantennas.

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Authors and Affiliations

  1. Laboratory of Hybrid Nanophotonics and Optoelectronics, ITMO University, St. Petersburg, 197101, Russia

    D. S. Gets, E. Yu. Tiguntseva, A. S. Berestennikov, T. G. Lyashenko, A. P. Pushkarev, S. V. Makarov & A. A. Zakhidov

  2. The University of Texas at Dallas, Richardson, TX, 75080, USA

    A. A. Zakhidov

Authors
  1. D. S. Gets
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  2. E. Yu. Tiguntseva
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  3. A. S. Berestennikov
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  4. T. G. Lyashenko
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  5. A. P. Pushkarev
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  6. S. V. Makarov
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  7. A. A. Zakhidov
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Correspondence to D. S. Gets.

Additional information

Original Russian Text © D.S. Gets, E.Yu. Tiguntseva, A.S. Berestennikov, T.G. Lyashenko, A.P. Pushkarev, S.V. Makarov, A.A. Zakhidov, 2018, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2018, Vol. 107, No. 12, pp. 768–775.

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Gets, D.S., Tiguntseva, E.Y., Berestennikov, A.S. et al. Photoinduced Migration of Ions in Optically Resonant Perovskite Nanoparticles. Jetp Lett. 107, 742–748 (2018). https://doi.org/10.1134/S002136401812007X

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  • DOI: https://doi.org/10.1134/S002136401812007X

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