Abstract
The molecular structure of neutral n-triacontanol mesophases at the n-hexane–water interface has been studied by diffuse X-ray scattering using synchrotron radiation. According to the experimental data, a transition to the multilayer adsorption of alkanol occurs at a temperature below the transition from a gas phase to a liquid Gibbs monolayer.
Similar content being viewed by others
References
J. W. Gibbs, Collected Works (Dover, New York, 1961), Vol. 1, p. 219.
A. W. Adamson, Physical Chemistry of Surfaces, 3rd ed. (Wiley, New York, 1976).
L. D. Landau and E. M. Lifshitz, Course of Theoretical Physics, Vol. 5: Statistical Physics (Nauka, Moscow, 1995; Pergamon, Oxford, 1980).
R. S. Hansen, J. Phys. Chem. 66, 410 (1962).
K. Motomura, J. Colloid Interface Sci. 64, 348 (1978).
K. Motomura, N. Matubayasi, M. Aratono, and R. Matuura, J. Colloid Interface Sci. 64, 356 (1978).
M. Lin, J. L Ferpo, P. Mansaura, and J. F. Baret, J. Chem. Phys. 71, 2202 (1979).
M. Aratono, T. Takiue, N. Ikeda, A. Nakamura, and K. Motomura, J. Phys. Chem. 97, 5141 (1993).
T. Takiue, T. Matsuo, N. Ikeda, K. Motomura, and M. Aratono, J. Phys. Chem. B 102, 4906 (1998).
A. M. Tikhonov and M. L. Schlossman, J. Phys.: Condens. Matter 19, 375101 (2007).
A. M. Tikhonov and M. L. Schlossman, J. Phys. Chem. B 107, 3344 (2003).
D. M. Mitrinovic, Z. J. Zhang, S. M. Williams, Z. Q. Huang, and M. L. Schlossman, J. Phys. Chem. B 103, 1779 (1999).
A. M. Tikhonov, J. Chem. Phys 124, 164704 (2006).
T. Takiue, A. Yanata, N. Ikeda, K. Motomura, and M. Aratono, J. Phys. Chem. 100, 13743 (1996).
A. Goebel and K. Lunkenheimer, Langmuir 13, 369 (1997).
A. M. Tikhonov, S. V. Pingali, and M. L. Schlossman, J. Chem. Phys. 120, 11822 (2004).
M. L. Schlossman, D. Synal, Y. Guan, M. Meron, G. Shea-McCarthy, Z. Huang, A. Acero, S. M. Williams, S. A. Rice, and P. J. Viccaro, Rev. Sci. Instrum. 68, 4372 (1997).
A. M. Tikhonov, JETP Lett. 104, 309 (2016).
A. M. Tikhonov, JETP Lett. 105, 775 (2017).
Y. Yoneda, Phys. Rev. 131, 2010 (1963).
S. K. Sinha, E. B. Sirota, S. Garoff, and H. B. Stanley, Phys. Rev. B 38, 2297 (1988).
B. K. Vainshtein, Diffraction of X Rays by Chain Molecules (Elsevier, Amsterdam, 1966).
G. Vignaud, A. Gibaud, J. Wang, S. K. Sinha, J. Daillant, G. Grubel, and Y. Gallot, J. Phys.: Condens. Matter 9, L125 (1997).
M. Li, D. J. Chaiko, A. M. Tikhonov, and M. L. Schlossman, Phys. Rev. Lett. 86, 5934 (2001).
M. Li, A. M. Tikhonov, and M. L. Schlossman, J. Europhys. Lett. 58, 80 (2002).
F. P. Buff, R. A. Lovett, and F. H. Stillinger, Phys. Rev. Lett. 15, 621 (1965).
D. K. Schwartz, M. L. Schlossman, E. H. Kawamoto, G. J. Kellogg, P. S. Pershan, and B. M. Ocko, Phys. Rev. A 41, 5687 (1990).
B. R. McClain, D. D. Lee, B. L. Carvalho, S. G. J. Mochrie, S. H. Chen, and J. D. Litster, Phys. Rev. Lett. 72, 246 (1994).
D. M. Mitrinovic, S. M. Williams, and M. L. Schlossman, Phys. Rev. E 63, 021601 (2001).
J. D. Weeks, J. Chem. Phys. 67, 3106 (1977).
A. Braslau, M. Deutsch, P. S. Pershan, A. H. Weiss, J. Als-Nielsen, and J. Bohr, Phys. Rev. Lett. 54, 114 (1985).
M. Tolan, Springer Tracts Mod. Phys. 148, 1 (1999).
A. M. Tikhonov, J. Phys. Chem. B 110, 2746 (2006).
A. M. Tikhonov, J. Phys. Chem. C 111, 930 (2007).
D. M. Mitrinovic, A. M. Tikhonov, M. Li, Z. Huang, and M. L. Schlossman, Phys. Rev. Lett. 85, 582 (2000).
D. M. Small, The Physical Chemistry of Lipids (Plenum, New York, 1986).
V. I. Marchenko, JETP Lett. 33, 381 (1981).
V. I. Marchenko, Sov. Phys. JETP 54, 605 (1981).
A. M. Tikhonov, J. Exp. Theor. Phys. 110, 1055 (2010).
H. M. McConnell, Ann. Rev. Phys. Chem. 42, 171 (1991).
S. Uredat and G. Findenegg, Langmuir 15, 1108 (1999).
A. W. Schuman, T. S. Bsaibes, and M. L. Schlossman, Soft Matter 10, 7353 (2014).
A. M. Tikhonov, M. Li, and M. L. Schlossman, J. Phys. Chem. B 105, 8065 (2001).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © A.M. Tikhonov, 2017, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2017, Vol. 106, No. 9, pp. 561–566.
Rights and permissions
About this article
Cite this article
Tikhonov, A.M. Diffuse X-ray scattering near a two-dimensional liquid–vapor phase transition at the n-hexane–water interface. Jetp Lett. 106, 576–581 (2017). https://doi.org/10.1134/S0021364017210135
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0021364017210135