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Solid–liquid phase transition in a Gibbs monolayer of melissic acid at the n-hexane–water interface

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Abstract

A sharp phase transition from a crystalline state with the area per molecule A = (17 ± 1) Å2 to a liquid state with A = (23 ± 1) Å2 at the n-hexane–water interface in a Gibbs monolayer of melissic acid has been revealed in data of X-ray reflectometry with the use of synchrotron radiation.

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References

  1. J. C. Earnshaw and C. J. Hughes, Phys. Rev. A 46, R4494 (1992).

    Article  ADS  Google Scholar 

  2. X. Z. Wu, E. B. Sirota, S. K. Sinha, B. M. Ocko, and M. Deutsch, Phys. Rev. Lett. 70, 958 (1993).

    Article  ADS  Google Scholar 

  3. J. T. Davies and E. K. Rideal, Interfacial Phenomena (Academic, New York, 1963).

    Google Scholar 

  4. D. M. Mitrinovic, A. M. Tikhonov, M. Li, Z. Huang, and M. L. Schlossman, Phys. Rev. Lett. 85, 582 (2000).

    Article  ADS  Google Scholar 

  5. Q. Lei and C. D. Bain, Phys. Rev. Lett. 92, 176103 (2004).

    Article  ADS  Google Scholar 

  6. M. L. Schlossman and A. M. Tikhonov, Ann. Rev. Phys. Chem. 59, 153 (2008).

    Article  ADS  Google Scholar 

  7. L. Tamam, D. Pontoni, Z. Sapir, Sh. Yefet, E. Sloutskin, B. M. Ocko, H. Reichert, and M. Deutsch, Proc. Nat. Acad. Sci. 108, 5522 (2011).

    Article  ADS  Google Scholar 

  8. A. M. Tikhonov, H. Patel, S. Garde, and M. L. Schlossman, J. Phys. Chem. B 110, 19093 (2006).

    Article  Google Scholar 

  9. D. M. Mitrinovic, Z. J. Zhang, S. M. Williams, Z. Q. Huang, and M. L. Schlossman, J. Phys. Chem. B 103, 1779 (1999).

    Article  Google Scholar 

  10. A. W. Adamson, Physical Chemistry of Surfaces, 3rd ed. (Wiley, New York, 1976).

    Google Scholar 

  11. T. Takiue, A. Yanata, N. Ikeda, K. Motomura, and M. Aratono, J. Phys. Chem. 100, 13743 (1996).

    Article  Google Scholar 

  12. M. L. Schlossman, M. Li, D. M. Mitrinovic, and A. M. Tikhonov, High Perform. Polym. 12, 551 (2000).

    Article  Google Scholar 

  13. M. L. Schlossman, D. Synal, Y. Guan, M. Meron, G. Shea-McCarthy, Z. Huang, A. Acero, S. M. Williams, S. A. Rice, and P. J. Viccaro, Rev. Sci. Instrum. 68, 4372 (1997).

    Article  ADS  Google Scholar 

  14. F. P. Buff, R. A. Lovett, and F. H. Stillinger, Phys. Rev. Lett. 15, 621 (1965).

    Article  ADS  Google Scholar 

  15. A. M. Tikhonov, J. Phys. Chem. C 111, 930 (2007).

    Article  Google Scholar 

  16. M. P. Gelfand and M. E. Fisher, Physica (Amsterdam) 166A, 1 (1990).

    Article  MathSciNet  ADS  Google Scholar 

  17. P. S. Pershan and M. L. Schlossman, Liquid Surfaces and Interfaces: Synchrotron X-ray Methods (Cambridge Univ. Press, Cambridge, 2012).

    Book  Google Scholar 

  18. J. Daillant, L. Bosio, B. Harzallah, and J. J. Benattar, J. Phys. II 1, 149 (1991).

    Google Scholar 

  19. D. M. Small, The Physical Chemistry of Lipids (Plenum, New York, 1986).

    Book  Google Scholar 

  20. A. M. Tikhonov, S. V. Pingali, and M. L. Schlossman, J. Chem. Phys. 120, 11822 (2004).

    Article  ADS  Google Scholar 

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Correspondence to A. M. Tikhonov.

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Original Russian Text © A.M. Tikhonov, 2015, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2015, Vol. 102, No. 8, pp. 620–625.

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Tikhonov, A.M. Solid–liquid phase transition in a Gibbs monolayer of melissic acid at the n-hexane–water interface. Jetp Lett. 102, 552–556 (2015). https://doi.org/10.1134/S0021364015200163

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  • DOI: https://doi.org/10.1134/S0021364015200163

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