Skip to main content
Log in

Spontaneous explosive crystallization and phase transformations in a selenium/copper bilayer nanofilm

  • Condensed Matter
  • Published:
JETP Letters Aims and scope Submit manuscript

Abstract

Spontaneous explosive crystallization in a selenium/copper bilayer nanofilm has been experimentally studied. It has been shown that the formation of a microcrack network in the selenium film is a decisive factor for spontaneous explosive crystallization. The microcrack network is an efficient channel for the relaxation of the collected energy of elastic stresses in the selenium film. The relaxation of this energy accelerates crystallization and transfers it to the explosive regime. It has been found that crystalline phases appearing in the products of the reaction after spontaneous explosive crystallization depend on the ratio of the thicknesses of the copper and selenium films.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. L. N. Aleksandrov, Crystallization and Recrystallization Kinetics of Semiconductor Films (Nauka, Novosibirsk, 1985) [in Russian].

    Google Scholar 

  2. V. A. Shklovskii and V. M. Kuz’menko, Sov. Phys. Usp. 32, 163 (1989).

    Article  ADS  Google Scholar 

  3. K. Ohdaira, N. Tomura, S. Ishii, et al., Electrochem. Solid State Lett. 14, H372 (2011).

    Article  Google Scholar 

  4. L. I. Kveglis, V. A. Seredkin, and A. V. Kuzovnikov, JETP Lett. 82, 22 (2005).

    Article  ADS  Google Scholar 

  5. V. D. Das and P. J. Lakshmi, Phys. Rev. B: Condens. Matter 37, 720 (1988).

    Article  ADS  Google Scholar 

  6. A. I. Olemskoi, A. V. Khomenko, and V. P. Koverda, Physica A 284, 79 (2000).

    Article  ADS  Google Scholar 

  7. D. Bensahel and G. Auvert, in Proceedings of Symposium, Boston, MA, Nov. 1–4, 1982 (1982), p. 165.

  8. O. Bostanjoglo and R. Liedtke, Phys. Status Solidi A 60, 451 (1980).

    Article  ADS  Google Scholar 

  9. V. P. Skripov and V. P. Koverda, Spontaneous Crystallization of Supercooled Liquids (Nauka, Moscow, 1984) [in Russian].

    Google Scholar 

  10. A. Mineo, A. Matsuda, T. Kurosi, et al., Solid State Commun. 13, 1307 (1973).

    Article  ADS  Google Scholar 

  11. R. Koba and C. E. Wickersham, Appl. Phys. Lett. 40, 672 (1982).

    Article  ADS  Google Scholar 

  12. R. Messier, T. Takamori, and R. Roy, Solid State Commun. 16, 311 (1975).

    Article  ADS  Google Scholar 

  13. S. M. Zharkov and L. I. Kveglis, Phys. Solid State 46, 969 (2004).

    Article  ADS  Google Scholar 

  14. S. A. Vekshinskii, New Method for Metallographic Investigation of Alloys (OGIZ, Moscow, Leningrad, 1944) [in Russian].

    Google Scholar 

  15. L. S. Palatnik and V. M. Kosevich, Sov. Phys. Crystallogr. 3, 716 (1958).

    Google Scholar 

  16. A. Matsuda, A. Mineo, T. Kurosi, et al., Solid State Commun. 13, 1165 (1973).

    Article  ADS  Google Scholar 

  17. J. C. Suits, Phys. Rev. 131, 588 (1963).

    Article  ADS  Google Scholar 

  18. V. M. Kuz’menko, B. G. Lazarev, V. I. Mel’nikov, et al., Ukr. Fiz. Zh. 21, 883 (1976).

    ADS  Google Scholar 

  19. L. N. Aleksandrov, in Crystal Growth (Moscow, 1983) [in Russian].

  20. V. A. Shklovskii, Sov. Phys. JETP 55, 311 (1982).

    Google Scholar 

  21. V. P. Koverda and V. P. Skripov, Sov. Phys. Crystallogr. 28, 106 (1983).

    Google Scholar 

  22. V. P. Koverda, V. P. Skripov, and N. M. Bogdanov, Dokl. Akad. Nauk SSSR 212, 1375 (1973).

    Google Scholar 

  23. Technical Description and User Manual of L-1250, L-305, N-1250 Series Motherboards (L-Card, Moscow, 1995).

  24. Handbook of Thin Film Technology, Ed. by L. Meissel and R. Glang (McGraw-Hill, New York, 1970; Sov. Radio, Moscow, 1977), Vol. 1.

    Google Scholar 

  25. Crystallographic and Crystal Chemical Database for Minerals and their Structural Analogues, http://data-base.iem.ac.ru/mincryst/rus/index.php.

  26. A. M. Zanin, D. P. Kiryukhin, I. M. Barkalov, et al., JETP Lett. 33, 320 (1981).

    ADS  Google Scholar 

  27. V. J. Kogai and A. V. Vakhrushev, J. Nanomech. Sci. Technol. 2, 55 (2011).

    Article  Google Scholar 

  28. Thin Films—Interdiffusion and Reactions, Ed. by J. M. Poate, K. N. Tu, and J. W. Mayer (Wiley, New York, 1978; Mir, Moscow, 1982).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to V. Ya. Kogai.

Additional information

Original Russian Text © V.Ya. Kogai, A.V. Vakhrushev, A.Yu. Fedotov, 2012, published in Pis’ma v Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2012, Vol. 95, No. 9, pp. 514–517.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kogai, V.Y., Vakhrushev, A.V. & Fedotov, A.Y. Spontaneous explosive crystallization and phase transformations in a selenium/copper bilayer nanofilm. Jetp Lett. 95, 454–456 (2012). https://doi.org/10.1134/S0021364012090068

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0021364012090068

Keywords

Navigation