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EPR diagnostics of the photosensitized generation of singlet oxygen on the surface of silicon nanocrystals

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Abstract

Electron paramagnetic resonance spectroscopy is used to determine the concentration of excited (singlet) molecular oxygen photosensitized by silicon nanocrystals. The generation of singlet oxygen in the porous silicon layers is studied quantitatively at various oxygen pressures and exciting light intensities with the use of the technique proposed. The experimental results indicate that silicon nanoclusters as the photosensitizers of singlet oxygen are promising for biomedical applications.

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References

  1. L. Packer and H. Sies, Singlet Oxygen, UV-A, and Ozone (Academic, London, 2000).

    Google Scholar 

  2. N. J. Turro, Modern Molecular Photochemistry (Univ. Sci., Sausalito, CA, 1991).

    Google Scholar 

  3. J. G. Moser, Photodynamic Tumor Therapy: 2nd and 3rd Generation Photosensitizers (Harwood Academic, Amsterdam, 1998).

    Google Scholar 

  4. D. Kovalev, E. Gross, N. Künzner, et al., Phys. Rev. Lett. 89, 137401 (2002).

  5. E. Gross, D. Kovalev, N. Künzner, et al., Phys. Rev. B 68, 115405 (2003).

  6. Ch. P. Poole, Electron Spin Resonance: Comprehensive Treatise on Experimental Techniques (Interscience-Wiley, New York, 1967).

    Google Scholar 

  7. O. Bisi, S. Ossicini, and L. Pavesi, Surf. Sci. Rep. 38, 1 (2000).

    Article  Google Scholar 

  8. J. L. Cantin, M. Schoisswohl, H. J. Bardeleben, et al., Phys. Rev. B 52, R11 599 (1995).

    Google Scholar 

  9. A. Carrington and A. D. McLachlan, Introduction to Magnetic Resonance with Applications to Chemistry and Chemical Physics (Harper and Row, New York, 1967).

    Google Scholar 

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Original Russian Text © E.A. Konstantinova, V.A. Demin, V.Yu. Timoshenko, P.K. Kashkarov, 2007, published in Pis’ma v Zhurnal Éksperimental’noĭ i Teoreticheskoĭ Fiziki, 2007, Vol. 85, No. 1, pp. 65–68.

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Konstantinova, E.A., Demin, V.A., Timoshenko, V.Y. et al. EPR diagnostics of the photosensitized generation of singlet oxygen on the surface of silicon nanocrystals. Jetp Lett. 85, 59–62 (2007). https://doi.org/10.1134/S0021364007010122

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  • DOI: https://doi.org/10.1134/S0021364007010122

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