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X-Ray Fluorescence Determination of Titanium, Zirconium, and Chromium in Titanium–Zirconium Sands of the Beshpagirskoe Deposit

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Inorganic Materials Aims and scope

Abstract

Gaining current information about the chemical composition of samples from different areas of the deposit during geological exploration necessitates the use of methods of rapid analysis, most often X-ray fluorescence analysis in combination with a method of external standard and its modifications. The existing certified methods assume the construction of calibration characteristics using reference standards. We propose to use a rapid method of X-ray fluorescence analysis (XRF) in a version of the method of fundamental parameters to determine nonferrous metals in the samples of titanium–zirconium sands of the Beshpagirskoe deposit and specified conditions of analysis. It is shown that, when using the method of fundamental parameters, the accuracy indicators are highly competitive with the indicators obtained by the certified method.

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REFERENCES

  1. Chefranova, A.V., Lalomov, A.V., Borisovsky, S.B., et al., Geochemical features of typomorphic metamorphic minerals of the Beshpagir deposit of rare metal-titanium placers, Akt. Probl. Gum. Estestv. Nauk, 2015, vol. 1, no. 10, pp. 46–51.

    Google Scholar 

  2. Bykhovsky, L.Z., Vasiliev, A.T., and Zabirko, A.G., On the project for the development of the Beshpagir complex placer raremetal deposit, Miner. Res. Ross. Ekon. Upravl., 2010, no. 2, pp. 68–75.

  3. Veremeeva, L.I., Ti-Zr placers in the south of Russia: Structural-geomorphological and mineralogical-technological aspects, Razved. Okhrana Nedr, 2011, no. 6, pp. 44–51.

  4. Kremenetsky, A.A., Veremeeva, L.I., Arkhipova, N.A., et al., Economic model of rational subsoil use on the example of the Stavropol Ti-Zr alluvial area, Razved. Okhrana Nedr, 2006, nos. 9–10, pp. 13–26.

  5. Sporykhina, L.V., Vasiliev, A.T., Bykhovskii, L.Z., et al., On the issue of improving the quality assessment of ore sands of titanium-bearing (titanium-containing) placers, Razved. Okhrana Nedr, 2016, no. 2, pp. 70–76.

  6. X-ray quantitative phase analysis (RKFA) of black concentrates from ore (Ti-Zr) sands (on the example of the Beshpagir deposit), Instruction NSOMMI, Moscow: VIMS, 2005, no. 54.

  7. Meftah, N. and Mahboub, M.S., Spectroscopic characterization of sands dunes minerals of El-Oued (Notheast Algerian Sahara) by FTIR, XRF and XRD analyses, Silicon, 2020, vol. 12, no. 1, pp. 147–153. https://doi.org/10.1007/s12633-019-00109-5

    Article  CAS  Google Scholar 

  8. Raneri, S., Botto, A., Campanella, B., et al., Increasing resolution in chemical mapping of geomaterials: From X-ray fluorescence to laser-induced breakdown spectroscopy, Spectrochim. Acta, Part B, 2022, vol. 194, p. 106482. https://doi.org/10.1016/j.sab.2022.106482

    Article  CAS  Google Scholar 

  9. Fazal, A.G., Shah, F., Miraj, M.A., et al., Geochemical analysis of cretaceous shales from the Hazara Basin, Pakistan: Provenance signatures and paleo-weathering conditions, J. Mar. Sci. Eng., 2022, vol. 10, no. 6, p. 800. https://doi.org/10.3390/jmse10060800

    Article  Google Scholar 

  10. NSAM (Instruction) 496-RS: Determination of the mass fraction of titanium, vanadium, iron and zirconium in rocks, ores and products of their processing by X-ray spectral fluorescence method, 2015.

  11. NSOMTI (Guidelines) 102: Selection of technological samples during geological exploration for ore minerals, 2014.

  12. Borkhodoev, V.Ya., Rentgenofluorestsentnyi analiz gornykh porod sposobom fundamental’nykh parametrov (X-ray Fluorescence Analysis of Rocks by the Method of Fundamental Parameters), Magadan: SVKNII FEB RAN, 1999.

  13. Mantler, M. and Kawahara, N., How accurate are modern fundamental parameter methods?, Rigaku J., 2004, vol. 21, no. 2, pp. 17–25.

    CAS  Google Scholar 

  14. Beckhoff, B., Kanngießer, B., Langhoff, N., et al., Handbook of Practical X-Ray Fluorescence Analysis, Berlin: Springer, 2006.

    Book  Google Scholar 

  15. RMG (Recommendations for Interstate Standartization) 61-2010: State system for ensuring the uniformity of measurements. Indicators of accuracy, correctness, precision of methods of quantitative chemical analysis. Assessment methods, 2013.

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Funding

The work was supported by the Ministry of Education and Science of the Russian Federation within the framework of the state task of the Kurnakov Institute of General and Inorganic Chemistry of the Russian Academy of Sciences.

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Correspondence to Ya. V. Kuminova or M. N. Filippov.

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The authors of this work declare that they have no conflicts of interest.

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Translated by Sh. Galyaltdinov

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Kuminova, Y.V., Filichkina, V.A., Filippov, M.N. et al. X-Ray Fluorescence Determination of Titanium, Zirconium, and Chromium in Titanium–Zirconium Sands of the Beshpagirskoe Deposit. Inorg Mater 59, 1470–1473 (2023). https://doi.org/10.1134/S0020168523140091

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  • DOI: https://doi.org/10.1134/S0020168523140091

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