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Content Analysis of Data on the Thermal Properties of Fluoride and Modified Fluoride Glasses

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Inorganic Materials Aims and scope

Abstract—

Using content analysis and the Python programming environment, we have found a number of general relationships determining the thermal properties of fluoride and modified fluoride glasses. Their compositions have been classified according to their glass transition temperature (Tg) and the difference between their crystallization onset temperature (Tx) and glass transition temperature: Tx – Tg. The use of Kauzmann’s rule for fluoride glasses, unmodified and modified with other halogens, has been shown to be more reliable if the Tg/Tm ratio is used, compared to the Tg/Tl ratio. We have qualitatively assessed how anion modification influences characteristic temperatures (glass transition temperature Tg, crystallization onset temperature Tx, crystallization peak temperature Tc, melting onset temperature Tm, and liquidus temperature Tl) and crystallization stability criteria (Hruby criterion K, Saad–Poulain criterion S, reduced thermal stability interval H, thermal stability interval Tx – Tg, and reduced glass transition temperatures Tg/Tm and Tg/Tl).

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Funding

This work was supported by the Russian Federation Ministry of Science and Higher Education as part of the state research targets for the Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, and the Prokhorov General Physics Institute, Russian Academy of Sciences.

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

    L. A. Vaimugin, K. S. Nikonov & M. N. Brekhovskikh

  2. Prokhorov General Physics Institute, Russian Academy of Sciences, 119991, Moscow, Russia

    L. V. Moiseeva

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  1. L. A. Vaimugin
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  2. K. S. Nikonov
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  3. L. V. Moiseeva
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  4. M. N. Brekhovskikh
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Correspondence to M. N. Brekhovskikh.

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Translated by O. Tsarev

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Vaimugin, L.A., Nikonov, K.S., Moiseeva, L.V. et al. Content Analysis of Data on the Thermal Properties of Fluoride and Modified Fluoride Glasses. Inorg Mater 59, 1002–1011 (2023). https://doi.org/10.1134/S0020168523090157

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