Abstract—
Layered double hydroxides containing zinc in the doubly charged cation position and aluminum in the triply charged cation position of brucite-like structures have been synthesized by a new method with the use of a low-temperature underwater plasma. Electrode materials were used as precursors. Well-crystallized layered double hydroxides and impurity phases have been obtained. The thermal stability of the materials has been shown to be due to the presence of impurity phases. The synthesized layered structures have a large specific surface area, which allows them to be used as fillers for polymer-matrix composites.
REFERENCES
Berlin, A.A. and Pakhomova, L.K., Polymer matrices for high-strength reinforced composites (a review), Vysokomol. Soedin., Ser. A, 1990, vol. 32, no. 7, pp. 1347–1382.
Pomogailo, A.D., Synthesis and intercalation chemistry of hybrid organo–inorganic nanocomposites, Polym. Sci., Ser. C, 2006, vol. 48, no. 1. pp. 85–119.
Ma, R., Takada, K., Fukuda, K., Iyi, N., Bando, Y., and Sasaki, T., Topochemical synthesis of monometallic (Co2+–Co3+) layered double hydroxide and its exfoliation into positively charged Co(OH)2 nanosheets, Angew. Chem., Int. Ed., 2008, vol. 47, no. 1, pp. 86–89. https://doi.org/10.1002/anie.200703941
Gu, F., Cheng, X., Wang, S., Wang, X., and Lee, P.S., Oxidative intercalation for monometallic Ni2+–Ni3+ layered double hydroxide and enhanced capacitance in exfoliated nanosheets, Small, 2015, vol. 11, no. 17, pp. 2044–2050. https://doi.org/10.1002/smll.201402603
Nagarajan, R., Gupta, P., Singh, P., and Chakraborty, P., An ethylene glycol intercalated monometallic layered double hydroxide based on iron as an efficient bifunctional catalyst, Dalton Trans., 2016, vol. 45, no. 43, pp. 17508–17520. https://doi.org/10.1039/C6DT03129C
Sertsova, A.A., Subcheva, E.N., and Yurtov, E.V., Synthesis and study of structure formation of layered double hydroxides based on Mg, Zn, Cu, and Al, Russ. J. Inorg. Chem., 2015, vol. 60, pp. 23–32. https://doi.org/10.1134/S0036023615010167
Nestroinaya, O.V., Ryl’tsova, I.G., Yapryntsev, M.N., and Lebedeva, O.E., Effect of the synthesis method on the phase composition and magnetism of layered double hydroxides, Inorg. Mater., 2020, vol. 56, pp. 747–753. https://doi.org/10.1134/S0020168520070109
Zhao, Y., Hu, H., Yang, X., Yan, D., and Dai, Q., Tunable electronic transport properties of 2D layered double hydroxide crystalline microsheets with varied chemical compositions, Small, 2016, vol. 12, no. 33, pp. 4471–4476. https://doi.org/10.1002/smll.201601354
Bukhtiyarova, M.V., A review on effect of synthesis conditions on the formation of layered double hydroxides, J. Solid State Chem., 2019, vol. 269, pp. 494–506. https://doi.org/10.1016/j.jssc.2018.10.018
Qu, J., Zhang, Q., Li, X., He, X., and Song, S., Mechanochemical approaches to synthesize layered double hydroxides: a review, Appl. Clay Sci., 2016, vol. 119, pp. 185–192. https://doi.org/10.1016/j.clay.2018.10.018
Chen, H., Zhao, Q., Gao, L., Ran, J., and Hou, Y., Water-plasma assisted synthesis of oxygen-enriched Ni–Fe layered double hydroxide nanosheets for efficient oxygen evolution reaction, ACS Sustain. Chem. Eng., 2019, vol. 7, no. 4, pp. 4247–4254. https://doi.org/10.1021/acssuschemeng.8b05953
Hur, T.B., Phuoc, T.X., and Chyu, M.K., Synthesis of Mg–Al and Zn–Al-layered double hydroxide nanocrystals using laser ablation in water, Opt. Lasers Eng., 2009, vol. 47, no. 6, pp. 695–700. https://doi.org/10.1016/j.optlaseng.2008.11.006
Agafonov, A.V., Sirotkin, N.A., Titov, V.A., and Khlyustova, A.V., Low-temperature underwater plasma as an instrument to manufacture inorganic nanomaterials, Russ. J. Inorg. Chem., 2022, vol. 67, pp. 253–261. https://doi.org/10.1134/S0036023622030020
Mascolo, G. and Marino, O., A new synthesis and characterization of magnesium–aluminium hydroxides, Mineral. Mag., 1980, vol. 43, no. 329, pp. 619–621. https://doi.org/10.1180/minmag.1980.043.329.09
Hur, T.B., Phuoc, T.X., and Chyu, M.K., New approach to the synthesis of layered double hydroxides and associated ultrathin nanosheets in de-ionized water by laser ablation, J. Appl. Phys., 2010, vol. 108, no. 11, p. 114312. https://doi.org/10.1063/1.3518510
Ahmed, A.A.A., Talib, Z.A., and Hussein, M.Z., Thermal, optical and dielectric properties of Zn–Al layered double hydroxide, Appl. Clay Sci., 2012, vol. 56, pp. 68–76. https://doi.org/10.1016/j.clay.2011.11.024
Abderrazek, K., Frini Srasra, N., and Srasra, E., Synthesis and characterization of [Zn–Al] layered double hydroxides: effect of the operating parameters, J. Chin. Chem. Soc., 2017, vol. 64, no. 3, pp. 346–353. https://doi.org/10.1002/jccs.201600258
Rodriguez-Rivas, F., Pastor, A., Barriga, C., Cruz-Yusta, M., Sánchez, L., and Pavlovic, I., Zn–Al layered double hydroxides as efficient photocatalysts for NOx abatement, Chem. Eng. J., 2018, vol. 346, pp. 151–158. https://doi.org/10.1016/j.cej.2018.04.022
Misol, A., Labajos, F.M., Morato, A., and Rives, V., Synthesis of Zn, Al layered double hydroxides in the presence of amines, Appl. Clay Sci., 2020, vol. 189, p. 105539. https://doi.org/10.1016/j.clay.2020.105538
Salih, E.Y., Sabri, M.F.M., Eisa, M.H., Sulaiman, K., Ramizy, A., Hussein, M.Z., and Said, S.M., Mesoporous ZnO/ZnAl2O4 mixed metal oxide-based Zn/Al layered double hydroxide as an effective anode material for visible light photodetector, Mater. Sci. Semicond. Process., 2021, vol. 121, p. 105370. https://doi.org/10.1016/j.mssp.2020.105370
Cavani, F., Trifiro, F., and Vaccari, A., Hydrotalcite-type anionic clays: preparation, properties and applications, Catal. Today, 1991, vol. 11, no. 2, pp. 173–301. https://doi.org/10.1016/0920-5861(91)80068-K
Roobottom, H.K., Jenkins, H.D.B., Passmore, J., and Glasser, L., Thermochemical radii of complex ions, J. Chem. Educat., 1999, vol. 76, no. 11, pp. 1570–1573. https://doi.org/10.1021/ed076p1570
Carrado, K., Kostapapas, A., and Suib, S., Layered double hydroxides (LDHs), Solid State Ionics, 1988, vol. 26, no. 2, pp. 77–86. https://doi.org/10.1016/0167-2738(88)90018-5
Puttaswamy, N.S. and Kamath, P.V., Reversible thermal behaviour of layered double hydroxides: a thermogravimetric study, J. Mater. Chem., 1997, vol. 7, no. 9, pp. 1941–1945. https://doi.org/10.1039/A701911D
Sing, K.S., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquérol, J., and Siemieniewska, T., Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity, Pure Appl. Chem., 1985, vol. 57, no. 4, pp. 603–619. https://doi.org/10.1351/pac198557040603
Bruggeman, P., Ribežl, E., Maslani, A., Degroote, J., Malesevic, A., Rego, R., Vierendeels, J., and Leys, C., Characteristics of atmospheric pressure air discharges with a liquid cathode and a metal anode, Plasma Sources Sci. Technol., 2008, vol. 17, no. 2, p. 025012. https://doi.org/10.1088/0963-0252/17/2/025012
Khlyustova, A., Sirotkin, N., Kraev, A., Titov, V., and Agafonov, A., Parameters of underwater plasma as a factor determining the structure of oxide (Al, Cu, and Fe), Materialia, 2021, vol. 16, p. 101081. https://doi.org/10.1016/j.mtla.2021.101081
ACKNOWLEDGMENTS
We are grateful to our colleagues at the Upper Volga Regional Physicochemical Research Center (Shared Research Facilities Center), Krestov Institute of Solution Chemistry, Russian Academy of Sciences, and at the Materials Research and Metallurgy Shared Research Facilities Center, Moscow Institute of Steel and Alloys (National University of Science and Technology).
Funding
This work was supported by the Russian Federation Ministry of Science and Higher Education, state research target no. 0092-2019-0003.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
The authors declare that they have no conflicts of interest.
Additional information
Translated by O. Tsarev
Rights and permissions
About this article
Cite this article
Agafonov, A.V., Sirotkin, N.A., Titov, V.A. et al. Underwater Plasma Synthesis of Zn–Al Layered Double Hydroxides. Inorg Mater 58, 1137–1144 (2022). https://doi.org/10.1134/S0020168522110012
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0020168522110012