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Caloric and Volumetric Properties of the Bi2O3–B2O3–BaO Glass-Forming System for Optical Applications

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Abstract—

The heat capacity and volumetric characteristics of 0.20Bi2O3⋅хBaO⋅(0.80 – х)B2O3 glasses containing 5, 10, 15, and 20 mol % BaO have been measured in the temperature range 300–1000 K. The results, in combination with the glass transition characteristics found, have been used to calculate the standard thermodynamic functions \(C_{p}^{^\circ }\)(Т), H°(T) − \(H_{l}^{^\circ }\)(0), S°(T) − \(S_{l}^{^\circ }\)(0), and G°(T) − \(H_{l}^{^\circ }\)(0); density ρ(T); and thermal expansion coefficient α(T) in the range from T → 0 to 900 K for the glasses and supercooled melts. Having a broad transmission window, as demonstrated by our spectroscopic measurements, the glasses have high crystallization resistance according to differential scanning calorimetry results.

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Funding

This work was supported by the Russian Science Foundation, grant. no. 20-73-10110.

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Authors and Affiliations

  1. Devyatykh Institute of Chemistry of High-Purity Substances, Russian Academy of Sciences, 603951, Nizhny Novgorod, Russia

    A. D. Plekhovich, E. E. Rostokina, M. E. Komshina, K. V. Balueva, K. F. Ignatova & A. M. Kut’in

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  1. A. D. Plekhovich
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  2. E. E. Rostokina
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  3. M. E. Komshina
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  4. K. V. Balueva
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  5. K. F. Ignatova
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Correspondence to A. D. Plekhovich.

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Translated by O. Tsarev

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Plekhovich, A.D., Rostokina, E.E., Komshina, M.E. et al. Caloric and Volumetric Properties of the Bi2O3–B2O3–BaO Glass-Forming System for Optical Applications. Inorg Mater 58, 736–743 (2022). https://doi.org/10.1134/S0020168522060097

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