Abstract—
We have investigated phase relations along a number of joins in the subsolidus region of the K2MoO4–BaMoO4–Gd2(MoO4)3 system using X-ray diffraction and differential thermal analysis and constructed its phase compatibility diagram. A triple molybdate with the composition KBaGd(MoO4)3 and a monoclinic scheelite-like structure (sp. gr. P21/n) has been synthesized. Codoping KBaGd(MoO4)3 with Er3+/Yb3+ ions, we have obtained an upconversion phosphor exhibiting anti-Stokes luminescence in the range 400–700 nm under IR excitation (λex = 977 nm). The synthesized phosphor has been characterized by X-ray diffraction, differential thermal analysis, and vibrational spectroscopy, and its luminescence spectra have been measured.
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REFERENCES
Trunov, V.K., Efremov, V.A., and Velikodnyi, Yu.A., Kristallokhimiya i svoistva dvoinykh molibdatov i vol’framatov (Crystal Chemistry and Properties of Double Molybdates and Tungstates), Leningrad: Nauka, 1986.
Morozov, V., Arakcheeva, A., Redkin, V., et al., Na2/7Gd4/7MoO4: a modulated scheelite-type structure and conductivity properties, Inorg. Chem., 2012, vol. 51, no. 9, pp. 5313–5324.https://doi.org/10.1021/ic300221m
Raskina, M.V., Morozov, V.A., Pavlenko, A.V., et al., Structure and Luminescent Properties of Solid Solutions Sm2 – xEux(MoO4)3, Russ. J. Inorg. Chem., 2015, vol. 60, no. 1, pp. 84–91.https://doi.org/10.1134/S0036023615010118
Zolotova, E.S., Rakhmanova, M.I., Sokolov, V.V., and Uskov, E.M., Influence of bismuth and calcium on the luminescence intensity of NaY1 – xEux(MoO4)2 phosphors, Inorg. Mater., 2011, vol. 47, no. 11, pp. 1249–1252.https://doi.org/10.1134/S0020168511100244
Kaminskii, A.A., Spektroskopiya kristallov (Spectroscopy of Crystals), Moscow: Nauka, 1975.
Kozhevnikova, N.M. and Mokhosoev, M.V., Troinye molibdaty (Ternary Molybdates), Ulan-Ude: Buryatsk. Gos. Univ., 2000.
Manashirov, O.Ya., Satarov, D.K., Smirnov, V.B., et al., Present state and prospects of the development of anti-Stokes luminophors for visualizers of IR radiation in the 0.8–13-μm region, Inorg. Mater., 1993, vol. 29, no. 10, pp. 1174–1176.
Ovsyankin, V.V. and Feofilov, P.P., Cooperative luminescence sensitization in rare-earth-doped crystals, Pis’ma Zh. Eksp. Teor. Fiz., 1966, vol. 4, no. 11, pp. 471–474.
Kuznetsov, S., Ermakova, Yu., Voronov, V., et al., Up-conversion quantum yields of SrF2:Yb3+,Er3+ sub-micron particles prepared by precipitation in water solution, J. Mater. Chem. C, 2018, vol. 6, no. 3, pp. 598–604.
Auzel, F.E., Materials and devices utilizing anti-Stokes charge transfer phosphors, TIIER, 1973, vol. 61, no. 6, pp. 87–120.
Auzel, F., Upconversion and anti-Stokes processes with f and d ions in solids, Chem. Rev., 2004, vol. 104, no. 1, pp. 139–173.
Lyapin, A.A., Ermakov, A.S., Kuznetsov, S.V., et al., Upconversion luminescence of CaF2–SrF2–ErF3 single crystals upon 1.5 μm laser excitation, J. Phys.: Conf. Ser., 2019, vol. 1410, paper 012086.https://doi.org/10.1088/1742-6596/1410/1/012086
Kazaryan, A.K., Timofeev, Yu.R., and Fok, M.V., Anti-Stokes conversion in rare-earth-containing phosphors, Tr. Fiz. Inst. im. P. N. Lebedeva, Akad. Nauk SSSR, 1986, vol. 175, pp. 4–65.
Evdokimov, A.A., Efremov, V.A., Trunov, V.K., et al., Soedineniya redkozemel’nykh elementov. Molibdaty, vol’framaty (Rare-Earth Compounds: Molybdates and Tungstates), Moscow: Nauka, 1991.
Kozhevnikova, N.M., Korsun, V.P., Mursakhanova, I.I., and Mokhosoev, M.V., Luminescence materials based on RE molybdates, J. Rare Earths, 1991, vol. 2, pp. 845–849.
Jiang, Y., Liu, Y., Liu, G., Dong, X., Wang, J., Yu, W., and Dong, Q., Surfactant-assisted hydrothermal synthesis of octahedral structured NaGd(MoO4)2:Eu3+/Tb3+ and tunable photoluminescent properties, Opt. Mater., 2014, vol. 36, pp. 1865–1870.https://doi.org/10.1016/j.optmat.2014.03.043
Georgobiani, A.N., Gruzintsev, A.N., Barthou, C., and Benalloul, P., Infrared luminescence of Y2O2S:Er3+ and Y2O3:Er3+, Inorg. Mater., 2004, vol. 40, no. 8, pp. 840–844.https://doi.org/10.1023/B:INMA.0000037930.59049.0b
Gruzintsev, A.N., Anti-Stokes luminescence of Y2O3:Er3+, Inorg. Mater., 2014, vol. 50, no. 1, pp. 58–62.https://doi.org/10.1134/S0020168514010087
Petrov, K.I., Poloznikova, M.E., Sharipov, Kh.T., and Fomichev, V.V., Kolebatel’nye spektry molibdatov i vol’framatov (Vibrational Spectra of Molybdates and Tungstates), Tashkent: FAN, 1990.
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This work was supported by the Russian Federation Ministry of Science and Higher Education (state research target for the Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, project no. 0273-2021-0008).
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Kozhevnikova, N.M. Synthesis and Characterization of a KBaGd(MoO4)3:Er3+/Yb3+ Phosphor with a Scheelite-Like Structure. Inorg Mater 58, 371–378 (2022). https://doi.org/10.1134/S0020168522040082
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DOI: https://doi.org/10.1134/S0020168522040082