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Extrinsic Absorption by Copper(II) Ions in Molybdenum-Containing Zinc Tellurite Glass

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Abstract—

Optical transmission of Cu2+-doped glass with the composition (TeO2)0.72(ZnO)0.18(MoO3)0.10 has been studied at dopant concentrations from 0.008 to 0.250 wt % and wavelengths from 0.45 to 2.80 μm. The transmission spectra of the glasses each have one strong absorption band peaking at ~819 nm. From the composition dependence of the absorption coefficient for a series of Cu2+-doped glass samples, we have calculated the specific absorption coefficient of Cu2+ ions, 4070 ± 83 dB/(km ppm) at 819 nm, and obtained its spectral dependence in the wavelength range studied.

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Funding

This work was supported by the Russian Federation Ministry of Science and Higher Education, state research target, basic research, project no. 0729-2020-0039.

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  1. Lobachevsky State University (National Research University), 603950, Nizhny Novgorod, Russia

    O. A. Zamyatin, D. A. Leksakov & Z. K. Nosov

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  1. O. A. Zamyatin
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Correspondence to O. A. Zamyatin.

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Zamyatin, O.A., Leksakov, D.A. & Nosov, Z.K. Extrinsic Absorption by Copper(II) Ions in Molybdenum-Containing Zinc Tellurite Glass. Inorg Mater 57, 1178–1183 (2021). https://doi.org/10.1134/S0020168521110145

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