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Effect of Ionizing Radiation on the Local Environment of Cerium-Related Emission Centers in Gd2SiO5:Ce Crystals

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Abstract—

We have studied absorption and luminescence spectra of gamma- and neutron-irradiated cerium-doped gadolinium oxyorthosilicate (Gd2SiO5:Ce) crystals. The results demonstrate that irradiation of the crystals removes oxygen ions from nine-coordinate oxygen structures around the silicon ions, increasing the number of seven-coordinate structures and transforming Ce1 centers into Ce2.

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Correspondence to I. Nuritdinov.

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Translated by O. Tsarev

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Nuritdinov, I., Esanov, Z.U. & Saidakhmedov, K.K. Effect of Ionizing Radiation on the Local Environment of Cerium-Related Emission Centers in Gd2SiO5:Ce Crystals. Inorg Mater 57, 1047–1051 (2021). https://doi.org/10.1134/S0020168521100095

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