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Luminescence Properties of Sol–Gel Derived Ceramic GdNbхTa1 –хO4 and YNbхTa1 –хO4 Solid Solutions

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Abstract

GdNbхTa1 –хO4 and YNbхTa1 –хO4 (x = 0–1) ceramic samples have been prepared by a sol–gel process, and the luminescence properties of the solid solutions have been studied under UV excitation. The results demonstrate that even a relatively small amount of tantalum (x = 0.9) in GdNbхTa1 –хO4 leads to a sharp increase in the luminescence intensity related to Nb4+–O centers, which exceeds the luminescence intensity in the GdNbO4 and GdTaO4 individual compounds by a factor of 3–6.5. The luminescence signal in the YNbхTa1 –хO4 solid solutions exceeds that in the YNbO4 and YTaO4 end-members at any Nb : Ta ratio, owing to energy transfer between Nb4+–O and Ta4+–O emission centers.

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REFERENCES

  1. Voloshyna, O., Boiaryntseva, I., Spassky, D., and Sidletskiy, O., Luminescence properties of the yttrium and gadolinium tantalo-niobates, Solid State Phenom., 2015, vol. 230, pp. 172–177.

    Article  Google Scholar 

  2. Blasse, G., The luminescence of closed-shell transition-metal complexes. New developments, in Luminescence and Energy Transfer, Structure and Bonding, vol. 42, Berlin: Springer, 1980, pp. 1–41.

  3. Brixner, L.H. and Chen, H.-y., On the structural and luminescent properties of the M' LnTaO4 rare earth tantalates, J. Electrochem. Soc.: Solid-State Sci.Technol., 1983, vol. 130, no. 12, pp. 2435–2443.

    CAS  Google Scholar 

  4. Blasse, G. and Bril, A., Luminescence of phosphors based on host lattices ABO4 (A is Sc, In; B is P, V, Nb), J. Chem. Phys., 1969, vol. 50, pp. 2974–2980.

    Article  CAS  Google Scholar 

  5. Gu, M., Xu, X., Liu, X., Qiu, L., and Zhang, R., Preparation and characterization of GdTaO4:Eu3+ sol–gel luminescence thin films, J. Sol–Gel Sci. Technol., 2005, vol. 35, pp. 193–196.

    Article  CAS  Google Scholar 

  6. Popovici, E.J., Imre-Lucaci, F., Muresan, L., Stefan, M., Bica, E., Grecu, R., and Indrea, E., Spectral investigations on niobium and rare earth activated yttrium tantalate powders, J. Optoelectron. Adv. Mater., 2008, vol. 10, no. 9, pp. 2334–2337.

    CAS  Google Scholar 

  7. Xiao, X. and Yan, B., Photoluminescent properties of Eu3+ (Dy3+)-activated YNbxTa1– xO4 and REVTa2O9 (RE = Y, La, Gd) phosphors from the hybrid precursors, Appl. Phys. A, 2007, vol. 88, pp. 333–339.

    Article  CAS  Google Scholar 

  8. Voloshyna, O.V., Boiaryntseva, I.A., Baumer, V.N., Ivanov, A.I., Korjik, M.V., and Sidletskiy, O.Ts., New, dense, and fast scintillators based on rare-earth tantalo-niobates, Nucl. Instrum. Methods Phys. Res.,Sect. A, 2014, vol. 764, pp. 227–231.

    CAS  Google Scholar 

  9. Blasse, G. and Bril, A., Luminescence phenomena in compounds with fergusonite structure, J. Lumin., 1970, no. 3, pp. 109–131.

  10. Voloshyna, O., Neicheva, S.V., Starzhinskiy, N.G., Zenya, I.M., Gridin, S.S., Baumer, V.N., and Sidletskiy, O.Ts., Luminescent and scintillation properties of orthotantalates with common formulae RETaO4 (RE = Y, Sc, La, Lu and Gd), Mater. Sci. Eng., B, 2013, vol. 178, no. 20, pp. 1491–1496.

    Article  CAS  Google Scholar 

  11. Pustovarov, V.A., Lyuminestsentsiya tverdykh tel. Uchebnoe posobie (Luminescence of Solids: A Learning Guide), Yekaterinburg: Ural’sk. Gos. Univ., 2017, pp. 58–96.

  12. Lammers, M.J.J. and Blasse, G., Energy transfer phenomena in Tb3+-activated gadolinium tantalate (GdTaO4), Mater. Res. Bull., 1984, vol. 19, no. 6, pp. 759–768.

    Article  CAS  Google Scholar 

  13. Panich, A.E. and Kupriyanov, M.F., Fizika i tekhnologiya segnetokeramiki (Physics and Technology of Ferroelectric Ceramics), Rostov-on-Don: Rostovsk. Gos. Univ., 1989.

  14. Karsu, E.C., Popovici, E.J., Morar, M., Ege, A., Can, N., Karali, T., and Indrea, E., Luminescence study of some yttrium tantalite-based phosphors, J. Lumin., 2011, vol. 131, pp. 1052–1057.

    Article  CAS  Google Scholar 

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Palatnikov, M.N., Smirnov, M.V., Masloboeva, S.M. et al. Luminescence Properties of Sol–Gel Derived Ceramic GdNbхTa1 –хO4 and YNbхTa1 –хO4 Solid Solutions. Inorg Mater 56, 437–442 (2020). https://doi.org/10.1134/S0020168520040111

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  • DOI: https://doi.org/10.1134/S0020168520040111

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