Abstract—
This paper presents modified views on the vapor–liquid–solid mechanism of nanowire growth, relying on new experimental data on the wettability of a crystal surface by metal catalyst droplets presaturated with the crystallizing substance.
Similar content being viewed by others
REFERENCES
Givargizov, E.I., Rost nitevidnykh i plastinchatykh kristallov iz para (Vapor Growth of Whiskers and Platelike Crystals), Moscow: Nauka, 1975.
Nebol’sin, V.A., Dolgachev, A.A., Dunaev, A.I., and Zavalishin, M.A., General trends in the growth of silicon micro- and nanowires, Izv. Ross. Akad. Nauk,Ser. Fiz., 2008, vol. 72, no. 9, pp. 1285–1288.
Dubrovskii, V.G., Nucleation Theory and Growth Nanostructures, Berlin: Springer, 2014, p. 601.
Naidich, Yu.V., Kontaktnye yavleniya v metallicheskikh rasplavakh (Contact Phenomena in Metallic Melts), Kiev: Naukova Dumka, 1972.
Nebol’sin, V.A., Dunaev, A.I., Samofalova, A.S., and Korneeva, V.V., Contact interaction in an M–SiO2 (M = metal catalyst for nanowire growth) system, Inorg. Mater., 2018, vol. 54, no. 6, pp. 558–563.
Nebol’sin, V.A., Shchetinin, A.A., and Natarova, E.I., Variation in silicon whisker radius during unsteady-state growth, Inorg. Mater., 1998, vol. 34, no. 2, pp. 87–89.
Nebol’sin, V.A., Dunaev, A.I., Tatarenkov, A.F., and Shmakova, S.S., Scenarios of stable NW VLS growth, J. Cryst. Growth, 2016, vol. 450, pp. 207–214.
Schmidt, V. et al., The shape of epitaxially grown silicon nanowires and the influence of line tension, J. Appl. Phys., 2005, vol. 80, no. 3, pp. 445–450.
Shchetinin, A.A., Darinskii, B.M., Kozenkov, O.D., and Nebol’sin, V.A., Mechanism for early stages of Si whisker growth, Izv. Akad. Nauk SSSR,Inorg. Mater., 1990, vol. 26, no. 7, pp. 1353–1357.
Nebol’sin, V.A. et al., Formation of “negative” silicon whiskers, Inorg. Mater., 2017, vol. 53, no. 8, pp. 775–780.
ACKNOWLEDGMENTS
In this study, we used equipment at the Nanoelectronics and Nanotechnological Devices Shared Research Facilities Center, Voronezh State Technical University.
Funding
This work was supported by the Russian Foundation for Basic Research, project no. 19-33-90219.
Author information
Authors and Affiliations
Corresponding author
Additional information
Translated by O. Tsarev
Rights and permissions
About this article
Cite this article
Nebol’sin, V.A., Vorob’ev, A.Y. & Swaikat, N. A New Understanding of the Vapor–Liquid–Solid Mechanism of Nanowire Growth. Inorg Mater 56, 346–352 (2020). https://doi.org/10.1134/S002016852004010X
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S002016852004010X