Skip to main content
SpringerLink
Log in

Synthesis and Luminescence Properties of a Li3Ba2La3(MoO4)8:Er3+ Phosphor with a Scheelite-Like Structure

  • Published:
Inorganic Materials Aims and scope

Abstract—Subsolidus phase relations in the Li2MoO4–BaMoO4–La2(MoO4)3 system have been studied by X-ray diffraction and differential thermal analysis. We have synthesized the ternary molybdate Li3Ba2La3(MoO4)8 doped with Er3+ and studied its luminescence properties and IR spectra.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.

Similar content being viewed by others

REFERENCES

  1. Trunov, V.K., Efremov, V.A., and Velikodnyi, Yu.A., Kristallokhimiya i svoistva dvoinykh molibdatov i vol’framatov (Crystal Chemistry and Properties of Double Molybdates and Tungstates), Leningrad: Nauka, 1986.

  2. Klevtsova, R.F., Vasil’ev, A.D., Glinskaya, L.A., et al., Crystal structure of the Li3Ba2R3(MoO4)8 (R = Gd,Tu) ternary molybdates, Zh. Strukt. Khim., 1992, vol. 33, no. 3, pp. 126–130.

    CAS  Google Scholar 

  3. Morozov, V., Arakcheeva, A., Redkin, V., et al., Na2/7Gd4/7MoO4: a modulated scheelite-type structure and conductivity properties, Inorg. Chem., 2012, vol. 51, no. 9, pp. 5313–5324. https://doi.org/10.1021/ic300221m

    Article  CAS  PubMed  Google Scholar 

  4. Raskina, M.V., Morozov, V.A., Pavlenko, A.V., et al., Structure and luminescent properties of solid solutions Sm2 – xEux(MoO4)3, Russ. J. Inorg. Chem., 2015, vol. 60, no. 1, pp. 84–91. https://doi.org/10.1134/S0036023615010118

    Article  CAS  Google Scholar 

  5. Zolotova, E.S., Rakhmanova, M.I., Sokolov, V.V., and Uskov, E.M., Influence of bismuth and calcium on the luminescence intensity of NaY1 – xEux(MoO4)2 phosphors, Inorg. Mater., 2011, vol. 47, no. 11, pp. 1249–1252.

    Article  CAS  Google Scholar 

  6. Kaminskii, A.A., Spektroskopiya kristallov (Spectroscopy of Crystals), Moscow: Nauka, 1975.

  7. Kozhevnikova, N.M. and Mokhosoev, M.V., Troinye molibdaty (Ternary Molybdates), Ulan-Ude: Buryatsk. Gos. Univ., 2000.

  8. Manashirov, O.Ya., Satarov, D.K., Smirnov, V.B., et al., Present state and prospects of the development of anti-Stokes luminophors for visualizers of IR radiation in the 0.8–13-μm region, Inorg. Mater., 1993, vol. 29, no. 10, pp. 1174–1176.

    Google Scholar 

  9. Auzel, F.E., Materials and devices using double-pumped phosphors with energy transfer, Proc. IEEE, 1973, vol. 61, no. 6, pp. 758–786.

    Article  CAS  Google Scholar 

  10. Kazaryan, A.K., Timofeev, Yu.R., and Fok, M.V., Anti-Stokes conversion in rare-earth-containing phosphors, Tr. Fiz. Inst. im. P. N. Lebedeva, Akad. Nauk SSSR, 1986, vol. 175, pp. 4–65.

    CAS  Google Scholar 

  11. Evdokimov, A.A., Efremov, V.A., Trunov, V.K., et al., Soedineniya redkozemel’nykh elementov. Molibdaty, vol’framaty (Rare-Earth Compounds: Molybdates and Tungstates), Moscow: Nauka, 1991.

  12. Kozhevnikova, N.M., Korsun, V.P., Mursakhanova, I.I., and Mokhosoev, M.V., Luminescence materials based on RE molybdates, J. Rare Earths, 1991, vol. 2, pp. 845–849.

    Google Scholar 

  13. Jiang, Y., Liu, Y., Liu, G., Dong, X., Wang, J., Yu, W., and Dong, Q., Surfactant-assisted hydrothermal synthesis of octahedral structured NaGd(MoO4)2:Eu3+/Tb3+ and tunable photoluminescent properties, Opt. Mater., 2014, vol. 36, pp. 1865–1870. https://doi.org/10.1016/j.optmat.2014.03.043

    Article  CAS  Google Scholar 

  14. Georgobiani, A.N., Gruzintsev, A.N., Barthou, C., and Benalloul, P., Infrared luminescence of Y2O2S:Er3+ and Y2O3:Er3+, Inorg. Mater., 2004, vol. 40, no. 8, pp. 840–844.

    Article  CAS  Google Scholar 

  15. Gruzintsev, A.N., Anti-Stokes luminescence of Y2O3:Er3+, Inorg. Mater., 2014, vol. 50, no. 1, pp. 58–62. https://doi.org/10.1134/S0020168514010087

    Article  CAS  Google Scholar 

  16. Kozhevnikova, N.M., Synthesis and phase formation study in K2MoO4–SrMoO4–R2(MoO4)3 systems (where R = Pr, Nd, Sm, Eu, and Gd), Russ. J. Inorg. Chem., 2012, vol. 57, no. 5, pp. 646–649.

    Article  CAS  Google Scholar 

  17. Kozhevnikova, N.M., Synthesis and study of RbSrR(MoO4)3 ternary molybdates (R = Nd, Sm, Eu, Gd) with scheelite-like structure, Russ. J. Inorg. Chem., 2013, vol. 58, no. 3, pp. 280–283. https://doi.org/10.1134/S0036023613020113

    Article  CAS  Google Scholar 

  18. Petrov, K.I., Poloznikova, M.E., Sharipov, Kh.T., and Fomichev, V.V., Kolebatel’nye spektry molibdatov i vol’framatov (Vibrational Spectra of Molybdates and Tungstates), Tashkent: FAN, 1990.

Download references

Author information

Authors and Affiliations

  1. Baikal Institute of Nature Management, Siberian Branch, Russian Academy of Sciences, ul. Sakh’yanovoi 6, 670047, Ulan-Ude, Buryat Republic, Russia

    N. M. Kozhevnikova

Authors
  1. N. M. Kozhevnikova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to N. M. Kozhevnikova.

Additional information

Translated by O. Tsarev

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kozhevnikova, N.M. Synthesis and Luminescence Properties of a Li3Ba2La3(MoO4)8:Er3+ Phosphor with a Scheelite-Like Structure. Inorg Mater 55, 607–611 (2019). https://doi.org/10.1134/S0020168519060098

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168519060098

Keywords:

Search

Navigation