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Electrical Transport and Photoelectric Properties of (As2Se3)1 –x(CdSe)x (x = 0.01, 0.03, 0.05) Glasses

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Abstract—

(As2Se3)1 –x(CdSe)x (x = 0.01, 0.03, 0.05) glass alloys have been prepared in the temperature range 500–700°C using As2Se3 and CdSe as master alloys. The electrical transport and photoelectric properties of the alloys containing 1, 3, and 5 mol % CdSe have been studied. The temperature dependences of electrical conductivity for the glass alloys demonstrate that they are high-resistivity p-type semiconductors. The results on the photoelectric properties of the alloys indicate that the materials are photosensitive in the wavelength range 0.75–0.82 μm and that their optical band gap varies from 1.51 to 1.65 eV.

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REFERENCES

  1. Hari, P., Cheneya, C., Luepkea, G., Singha, S., Tolka, N., Sanghera, J.S., and Aggarwal, D., Wavelength selective materials modification of bulk As2S3 and As2Se3 by free electron laser irradiation, J. Non-Cryst. Solids, 2000, vol. 270, pp. 265–268.

    Article  CAS  Google Scholar 

  2. Sati Dinesh Chandra, Kumar Rajendra, and Mehra Ram Mohan, Influence of thickness on optical properties of a:As2Se3 thin films, Turk J. Phys., 2006, vol. 30, pp. 519–527.

    Google Scholar 

  3. Lovu, M., Shutov, A., Rebeja, S., Colomeyco, E., and Popescu, M., Effect of metal additives on photodarkening kinetics in amorphous As2Se3 films, J. Optoelectron. Adv. Mater., 2000, vol. 2, pp. 53–58.

    Google Scholar 

  4. Fu, L.B., Rochette, M., Ta’eed, V., Moss, D., and Eggleton, B.J., Investigation of self-phase modulation based optical regeneration in single mode As2Se3 chalcogenide glass fiber, Opt. Express, 2005, vol. 13, pp. 7637–7640.

    Article  CAS  PubMed  Google Scholar 

  5. Asobe, M., Ohara, T., Yokohama, I., and Kaino, T., Fabrication of Bragg grating in chalcogenide glass fibre using the transverse holographic method, Electron. Lett., 1996, vol. 32, pp. 1611–1613.

    Article  CAS  Google Scholar 

  6. Efros, Al.L. and Rosen, M., The electronic structure of semiconductor nanocrystals, Annu. Rev. Mater. Sci., 2000, vol. 30, pp. 475–521.

    Article  CAS  Google Scholar 

  7. Aliev, I.I., Physicochemical principles underlying the preparation of new materials in systems of arsenic chalcogenides with cadmium, indium, and thallium chalcogenides, Doctoral (Chem.) Dissertation, Baku: Inst. of Inorganic and Physical Chemistry, Acad. Sci. of Azerbaijan, 1992.

  8. Aliev, I.I., Rustamov, P.G., Il’yasov, T.M., and Maksudova, T.F., Phase diagram of the As2Se3–CdSe system, Izv. Akad. Nauk SSSR, Neorg. Mater., 1987, vol. 23, no. 12, pp. 1965–1967.

    CAS  Google Scholar 

  9. Dembovskii, S.A. and Vaipolin, A.A., Properties of As2Se3 crystals, Fiz. Tverd. Tela (Leningrad), 1964, vol. 6, no. 6, pp. 1769–1772.

    CAS  Google Scholar 

  10. Khvorestanko, A.S., Arsenic chalcogenides, in Fizicheskie i khimicheskie svoistva tverdogo tela (Physical and Chemical Properties of Solids), Moscow, 1972.

    Google Scholar 

  11. Abrikosov, N.Kh., Botkina, V.F., Poretskaya, A.V., and Skudnova, E.V., Poluprovodnikovye soedineniya, ikh poluchenie i svoistva (Preparation and Properties of Compound Semiconductors), Moscow: Nauka, 1967.

  12. Ormont, B.F., Struktury neorganicheskikh veshchestv (Structures of Inorganic Substances), Moscow: Gostekhizdat, 1950.

  13. Okhotin, A.S., Pushkarskii, A.S., Borovikova, R.P., and Simonov, V.A., Metody izmereniya kharakteristik termoelektricheskikh materialov i preobrazovatelei (Methods for Measuring Characteristics of Thermoelectric Materials and Converters), Moscow: Nauka, 1974.

  14. Ryvkin, S.M., Fotoelektricheskie yavleniya v poluprovodnikakh (Photoelectric Phenomena in Semiconductors), Moscow: Fizmatgiz, 1963.

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Ahmedova, C.A. Electrical Transport and Photoelectric Properties of (As2Se3)1 –x(CdSe)x (x = 0.01, 0.03, 0.05) Glasses. Inorg Mater 55, 506–508 (2019). https://doi.org/10.1134/S0020168519040022

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  • DOI: https://doi.org/10.1134/S0020168519040022

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