Skip to main content
SpringerLink
Log in

Effect of Iron Oxalate Additions on the Phase Composition of Combustion Products of Silicon–Carbon Mixtures in Nitrogen

  • Published:
Inorganic Materials Aims and scope

Abstract—

We have examined the effect of iron oxalate (Fe2(C2O4)3 · 5H2O) additions on the phase composition of combustion products of silicon–carbon mixtures in nitrogen. The phase composition of the combustion products has been determined as a function of starting-mixture composition and nitrogen pressure. We have investigated the microstructure of the synthesized powders. The addition of SiO2 to the starting mixture has been shown to increase the percentage of Si2N2O in the combustion products.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.
Fig. 6.
Fig. 7.

Similar content being viewed by others

REFERENCES

  1. Barinova, T.V. and Borovinskaya, I.P., Some specific features of the combustion of silicon in nitrogen in the presence of organic additives, Inorg. Mater., 2014, vol. 50, no. 11, pp. 1078–1082. https://doi.org/10.1134/S0020168514100045

    Article  CAS  Google Scholar 

  2. Barinova, T.V. and Borovinskaya, I.P., Combustion of silicon powders containing organic additives in nitrogen gas under pressure: 2. Composition of combustion products, Int. J. Self-Propag. High-Temp. Synth., 2009, vol. 18, no. 1, pp. 30–33. https://doi.org/10.3103/S1061386209010063

    Article  CAS  Google Scholar 

  3. Barinova, T.V., Borovinskaya, I.P., Barinov, Yu.N., Kovalev, I.D., and Shchukin, A.S., Polycrystalline silicon nitride fibers by SHS: impact of ammonium acetate and ferric chloride additives, Int. J. Self-Propag. High-Temp. Synth., 2018, vol. 27, no. 2, pp. 92–97. https://doi.org/10.3103/S106138621802005X

    Article  CAS  Google Scholar 

  4. Agrafiotis, Ch.C., Lis, J., Puszynski, J.A., and Hlavacek, V., Combustion synthesis of silicon nitride–silicon carbide composites, J. Am. Ceram. Soc., 1990, vol. 73, no. 11, pp. 3214–3517.

    Article  Google Scholar 

  5. Kata, D. and Pumpuch, R., Combustion synthesis of multiphase powders in the Si–C–N system, Solid State Ionics, 1997, vols. 101–103, pp. 65–70.

    Google Scholar 

  6. Li, X., Zhang, L., and Yin, X., Study on in-situ reaction synthesis and mechanical properties of Si2N2O ceramic, Ceram. Int., 2013, vol. 39, pp. 3035–3041. https://doi.org/10.1016/j.ceramint.2012.09.082.

    Article  CAS  Google Scholar 

  7. Cheng, H., Li, Y., Kroke, E., and Herkenhoff, S., In situ synthesis of Si2N2O/Si3N4 composite ceramics using polysilyloxycarbodiimide precursors, J. Eur. Ceram. Soc., 2013, vol. 33, pp. 2181–2189. https://doi.org/10.1016/j.jeurceramsoc.2013.02.029.

    Article  CAS  Google Scholar 

  8. Studenikin, I.A. and Grachev, V.V., Synthesis of silicon oxynitride by infiltration-mediated combustion, Int. J. Self-Propag. High-Temp. Synth., 2008, vol. 17, no. 4, pp. 237–241. https://doi.org/10.3103/S106138620804006

    Article  CAS  Google Scholar 

  9. Shkarin, A.V., Zhabrova, G.M., Topor, N.D., and Kushnarev, M.Ya., Thermal stability and chemical transformations of oxalates, Izv. Tomsk. Politekh. Inst., 1969, vol. 199, pp. 105–111.

    CAS  Google Scholar 

  10. Suzdalev, I.P., Maksimov, Yu.V., Imshennik, V.K., Novichikhin, S.V., Matveev, V.V., Tret’yakov, Yu.D., Lukashin, A.V., Eliseev, A.A., Malygin, A.A., and Sosnov, E.A., Structural hierarchy and magnetic properties of nanostructured iron oxides, Nanotechnol. Russ., 2006, vol. 1, nos. 1–2, pp. 134–141.

    Google Scholar 

  11. Kosolapova, T.Ya., Andreeva, T.V., Bartnitskaya, T.B., Gnesin, G.G., et al., Nemetallicheskie tugoplavkie soedineniya (Nonmetallic Refractory Compounds), Moscow: Metallurgiya, 1985.

  12. Kolasinski, K.W., Catalytic growth of nanowires: vapor–liquid–solid, vapor–solid–solid, solution–liquid–solid and solid–liquid–solid growth, Curr. Opin. Solid State Mater. Sci., 2006, vol. 10, pp. 182–191. org/ https://doi.org/10.1016/j.cossms.2007.03.002

  13. Givargizov, E.I. and Chernov, A.A., Growth rate of whisker crystals by the vapor–liquid–solid mechanism and the role of surface energy, Kristallografiya, 1973, vol. 18, no. 1, pp. 147–149.

    CAS  Google Scholar 

  14. Chukhlomina, L.N., Vitushkina, O.G., and Vereshchagin, V.I., Self-propagating high-temperature synthesis of silicon nitride ceramic mix using ferro-silicon and ilmenite, Steklo Keram., 2010, no. 9, pp. 15–18.

Download references

Author information

Authors and Affiliations

  1. Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, ul. Akademika Osip’yana 8, 142432, Chernogolovka, Moscow oblast, Russia

    T. V. Barinova, V. Yu. Barinov & I. D. Kovalev

Authors
  1. T. V. Barinova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Yu. Barinov
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. I. D. Kovalev
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to T. V. Barinova.

Additional information

Translated by O. Tsarev

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Barinova, T.V., Barinov, V.Y. & Kovalev, I.D. Effect of Iron Oxalate Additions on the Phase Composition of Combustion Products of Silicon–Carbon Mixtures in Nitrogen. Inorg Mater 55, 37–41 (2019). https://doi.org/10.1134/S0020168519010023

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0020168519010023

Keywords:

Search

Navigation