Inorganic Materials

, Volume 54, Issue 12, pp 1199–1204 | Cite as

Phase Relations along the Cu2S(Sb2S3, PbSb2S4, Pb5Sb4S11)–PbCuSbS3 Joins in the Pseudoternary System Cu2S–PbS–Sb2S3 and Physical Properties of (Sb2S3)1 –x(PbCuSbS3)x Solid Solutions

  • O. M. Aliyev
  • D. S. Ajdarova
  • R. M. Agayeva
  • T. F. Maksudova
  • Sh. H. MamedovEmail author


Phase relations along the Cu2S(Sb2S3, PbSb2S4, Pb5Sb4S11)–PbCuSbS3 joins in the pseudoternary system Cu2S–PbS–Sb2S3 have been studied using a variety of physicochemical characterization techniques (differential thermal analysis, X-ray diffraction, microstructural analysis, microhardness tests, and immersion density measurements). All of the joins have been shown to be pseudobinary, with eutectic phase relations. We have investigated the electrical transport properties of (Sb2S3)1 – x(PbCuSbS3)x solid solutions, which have been shown to be p-type semiconductors.


solid solutions pseudoternary system Cu2S–PbS–Sb2S3 semiconductors physicochemical analysis 



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© Pleiades Publishing, Inc. 2018

Authors and Affiliations

  • O. M. Aliyev
    • 1
  • D. S. Ajdarova
    • 1
  • R. M. Agayeva
    • 2
  • T. F. Maksudova
    • 1
  • Sh. H. Mamedov
    • 1
    Email author
  1. 1.Nagiyev Institute of Catalysis and Inorganic Chemistry, Academy of Sciences of AzerbaijanBakuAzerbaijan
  2. 2.Azerbaijani State Pedagogical UniversityBakuAzerbaijan

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