Abstract
We have studied the optical properties of copper-doped lithium niobate crystals using semiconductor light-emitting diodes and lasers emitting in the visible and ultraviolet spectral regions as excitation sources. The results demonstrate that, at an excitation frequency approaching the frequency of electronic absorption in copper ions, there is discrete resonance Raman scattering in the form of a frequency comb. The observed Raman satellites of discrete light scattering are due to polar longitudinal A1 optical modes of the lithium niobate single crystal. Under excitation by a light-emitting diode with a wavelength of 520 nm, we observe a sharp increase in discrete light scattering intensity in comparison with the photoluminescence excited by shorter wavelength excitation sources.
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Sidorov, N.V., Palatnikov, M.N., Serebryakov, Yu.A., Lebedeva, E.L., and Kalinnikov, V.T., Effect of nonstoichiometry on the structure, properties, and Raman spectra of lithium niobate crystals, Inorg. Mater., 1997, vol. 33, no. 4, pp. 419–427.
Sidorov, N.V., Volk, T.R., Mavrin, B.N., and Kalinnikov, V.T., Niobat litiya: defekty, fotorefraktsiya, kolebatel’nyi spektr, polyaritony (Lithium Niobate: Defects, Photorefractive Properties, Vibrational Spectrum, and Polaritons), Moscow: Nauka, 2003.
Sidorov, N.V. and Serebryakov, Yu.A., Investigation of structural peculiarities of impure lithium niobate crystals by Raman spectroscopy, Vibr. Spectrosc., 1994, vol. 6, no. 2, pp. 215–223.
Smolenskii, G.A., Bokov, V.A., Isupov, V.A., Krainik, N.N., Pasynkov, R.E., and Shur, M.S., Segnetoelektriki i antisegnetoelektriki (Ferroelectrics and Antiferroelectrics), Leningrad: Nauka, 1971.
Myasnikova, T.P. and Myasnikova, A.E., Optical spectra of lithium niobate, Phys. Solid State, 2015, vol. 45, no. 12, pp. 2338–2341.
Krindach, D.P., Kholodnykh, A.I., and Churin, A.A., Parametric luminescence lineshape in lithium niobate crystals, Kvantovaya Elektron. (Moscow), 1972, no. 7, pp. 71–73.
Kruk, A.A., Sidorov, N.V., Yanichev, A.A., and Palatnikov, M.N., Effect of excitation wavelength on Raman spectra of copper–doped lithium niobate crystals, Zh. Prikl. Spektrosk., 2014, vol. 81, no. 1, pp. 5–10.
Sidorov, N.V., Yanichev, A.A., Chufyrev, P.G., Palatnikov, M.N., Mavrin, B.N., and Bormanis, K., Microand nano–structures of nominally pure stoichiometric lithium niobate single crystal in Raman spectra, Integr. Ferroelectr., 2009, vol. 109, no. 1, pp. 48–54.
Palatnikov, M.N., Sidorov, N.V., and Makarova, O.V., Particularities of optical characteristics of lithium niobate single crystals with different chemical compound, Herald Kola Sci. Centre Russ. Akad. Sci., 2016, vol. 4, no. 27, pp. 99–107.
Basiev, T.T., Sobol, A.A., Zverev, P.G., Ivleva, L.I., Osiko, V.V., and Powell, R.C., Raman spectroscopy of crystals for stimulated Raman scattering, Opt. Mater., 1999, vol. 11, no. 4, pp. 307–314.
Gorelik, V.S. and Sverbil’, P.P., Raman scattering by longitudinal and transverse optical vibrations in lithium niobate single crystals, Inorg. Mater., 2015, vol. 51, no. 11, pp. 1104–1110.
Gorelik, V.S., Sidorov, N.V., and Vodchits, A.I., Optical properties of lithium niobate and lithium tantalate crystals with impurities and defects, Phys. Wave Phenom., 2017, vol. 25, no. 1, pp. 10–19.
Sidorov, N.V., Palatnikov, M.N., Gabrielyan, V.T., Chufyrev, P.G., and Kalinnikov, V.T., Raman spectra and structural perfection of nominally pure lithium niobate crystals, Inorg. Mater., 2007, vol. 43, no. 1, pp. 60–67.
Litvinova, V.A. and Litvinova, M.N., Change in the structural imperfection of lithium niobate crystals doped with zinc, Crystallogr. Rep., 2015, vol. 60, no. 1, pp. 52–56.
Nikonorov, N.V., Sidorov, A.I., Tsekhomskii, V.A., and Shakhverdov, T.A., Broadband copper luminescence in potassium–aluminum borate glasses, Opt. Spectrosc., 2013, vol. 114, no. 3, pp. 379–383.
Demicheva, I.A., Sidorova, A.I., Nikonorova, N.V., and Shakhverdova, T.A., Formation of luminescent optical waveguides in silicate glass as a result of incorporation of copper ions via ion exchange, Nauchno–Tekh. Vestn. Inf. Tekhnol., Mekh. Opt., 2015, vol. 15, no. 1, pp. 54–59.
Gal’chenko, T.G. and Vorob’ev, V.A., Photoluminescence of ZnS:Cu,Pb solid solutions, Vestn. NGU, Ser.: Fiz., 2013, vol. 8, no. 2, pp. 6–10.
Mambetova, K.M. and Shandarov, S.M., Formation of strong electric fields in copper–doped lithium niobate crystals, Izv. Samarsk. Nauchn. Tsentra Ross. Akad. Nauk, 2013, vol. 15, no. 6, pp. 113–116.
Voskresenskii, V.M., Starodub, O.R., Sidorov, N.V., Palatnikov, M.N., and Mavrin, B.N., Modeling of cluster formation in nonlinear optical lithium niobate crystal, Crystallogr. Rep., 2011, vol. 56, no. 2, pp. 221–226.
Sandler, V.A., Sidorov, N.V., and Palatnikov, N.M., Dielektricheskie kristally: simmetriya i fizicheskie svoistva (Dielectric Crystals: Symmetry and Physical Properties), Apatity: Kol’sk. Nauchn. Tsentr Ross. Akad. Nauk, 2010, part 2.
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Original Russian Text © V.S. Gorelik, M.N. Palatnikov, A.Yu. Pyatyshev, N.V. Sidorov, A.V. Skrabatun, 2018, published in Neorganicheskie Materialy, 2018, Vol. 54, No. 10, pp. 1071–1078.
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Gorelik, V.S., Palatnikov, M.N., Pyatyshev, A.Y. et al. Optical Properties of Copper-Doped Lithium Niobate Crystals. Inorg Mater 54, 1013–1020 (2018). https://doi.org/10.1134/S0020168518100072
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DOI: https://doi.org/10.1134/S0020168518100072